|本期目录/Table of Contents|

[1]张晋菲,占美清,吕汪洋,等.锌酞菁纳米催化剂的形貌调控及光活性研究[J].浙江理工大学学报,2016,35-36(自科6):861-866.
 ZHANG Jinfei,ZHAN Meiqing,L  Wangyang,et al.Study on Morphology Control and Light Activity of ZnPc Catalyst[J].Journal of Zhejiang Sci-Tech University,2016,35-36(自科6):861-866.
点击复制

锌酞菁纳米催化剂的形貌调控及光活性研究()
分享到:

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第35-36卷
期数:
2016年自科6期
页码:
861-866
栏目:
出版日期:
2016-11-10

文章信息/Info

Title:
Study on Morphology Control and Light Activity of ZnPc Catalyst
文章编号:
1673-3851 (2016) 06-0861-06
作者:
张晋菲占美清吕汪洋陈文兴
浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州 310018
Author(s):
ZHANG Jinfei ZHAN Meiqing L  Wangyang CHEN Wenxing
Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of  Education, Zhejiang Sci-Tech University, Hangzhou 310018,China
关键词:
锌酞菁表面活性剂溶剂热光催化氧化
分类号:
TS195.644
文献标志码:
A
摘要:
使用乙二醇、醋酸锌、钼酸铵以及阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)通过溶剂热方法合成了形貌可控的锌酞菁纳米催化剂,研究了催化剂的表面形貌特征、可见光吸收性能以及光催化活性,探索了在CTAB存在下锌酞菁的形貌形成机理。结果表明:在CTAB存在下溶剂热合成的锌酞菁颗粒为直径约100 nm的小球,表面呈现出褶皱结构,球与球之间存在空隙并且均匀分布,在2θ=33.2°衍射角处有一个较明显的衍射峰,可见光催化活性较好,在光照条件下8 h可以将RhB染料完全降解,并且推测出纳米催化材料的形成过程是胶束形成过程。

参考文献/References:

[1] YUAN R, GUAN R, LIU P, et al. Photocatalytic treatment of wastewater from paper mill by TiO2 loaded on activated carbon fibers[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2007,293(1):80-86.
[2] LEGRINI O, OLIVEROS E, BRAUN A M. Photochemical processes for water treatment[J]. Chemical Reviews,1993,93(2):671-698.
[3] OPPENLNDER T. Photochemical Purification of Water and Air: Advanced Oxidation Processes(AOPs)Principles, Reaction Mechanisms, Reactor Concepts[M]. John Wiley & Sons,2003.
[4] MOSER F H, THOMAS A L. Phtalocyanine compounds[J]. Journal of Chemical Education,1964,41(5):245.
[5] BRACH P J, GRAMMATICA S J, OSSANNA O A, et al. Improved synthesis of metalfree phthalocyanines[J]. Journal of Heterocyclic Chemistry,1970,7(6):1403-1405.
[6] BYRNE G T, LINSTEAD R P, LOWE A R. The preparation of phthalocyanine and some metallic derivatives from ocyanobenzamide and phthalimide[J]. Journal of the Chemical Society,1934:1017-1022.
[7] METZ J, SCHNEIDER O, HANACK M. Synthesis and properties of substituted(phthalocyaninato)iron andcobalt compounds and their pyridine adducts[J]. Inorganic Chemistry,1984,23(8):1065-1071.
[8] NEMYKIN V N, LUKYANETS E A. Synthesis of substituted phthalocyanines[J]. Arkivoc,2010,1:136-208.
[9] YAO W T, YU S H, LIU S J, et al. Architectural control syntheses of CdS and CdSenanoflowers, branched nanowires, and nanotrees via a solvothermal approach in a mixed solution and their photocatalyticproperty[J]. Journal of Physical Chemistry B,2006,110(24):11704-11710.
[10] 占美清.锌酞菁的溶剂热制备及其形貌与可见光催化性能研究[D].杭州:浙江理工大学,2013.
[11] LIYANAARACHCHI T P, VALSARAJ K T, HUNG F R. Adsorption of naphthalene and ozone on atmospheric air/ice interfaces coated with surfactants: a molecular simulation study[J]. Journal of Physical Chemistry A,2012,116:2519-2528
[12] POLAVARAPU P L, VIJAY R. Chiroptical spectroscopy of surfactants[J]. Journal of Physical Chemistry A,2012,116:51125118.
[13] LEE C, DOONG R. Enhanced dechlorination of tetrachloroethylene by zerovalent silicon in the presence of polyethylene glycol under anoxic conditions[J]. Environmental Science and Technology,2011,45(6):2301-2307.

相似文献/References:

[1]崔静,王騊,王晟.微乳液法合成MgCO 3·3H 2O纳米棒及其应用拓展[J].浙江理工大学学报,2015,33-34(自科2):183.
 CUI Jing,WANG Tao,WANG Sheng.Synthesis of MgCO 3·3H 2O Nanorod via Micro emulsion Method and Research on Its Applications[J].Journal of Zhejiang Sci-Tech University,2015,33-34(自科6):183.
[2]顾楠楠,占美清,吕汪洋,等.形貌可控锌酞菁纳米催化剂的制备及可见光活性[J].浙江理工大学学报,2016,35-36(自科3):355.
 GU Nannan,ZHAN Meiqing,L  Wangyang,et al.Preparation and Visible Light Activity of Shape Controlled  Zinc Phthalocyanine Nanocatalyst[J].Journal of Zhejiang Sci-Tech University,2016,35-36(自科6):355.
[3]刘娟娟,裴刘军,吴雪原,等.活性染料在硅基非水介质中增溶性能的研究[J].浙江理工大学学报,2016,35-36(自科5):643.
 LIU Juanjuan,PEI Liujun,WU Xueyuan,et al.Study on Solubilization Property of Reactive Dyes in  Silicone Based Non aqueous Medium[J].Journal of Zhejiang Sci-Tech University,2016,35-36(自科6):643.
[4]王新英,陈涛,蒋丽源,等.短氟碳链季铵盐表面活性剂的合成及性能研究[J].浙江理工大学学报,2017,37-38(自科2):202.
 WANG Xinyin,CHEN Tao,JIANG Liyuan,et al.Synthesis and Properties of Quaternary Ammonium SurfactantsContaining Short Fluorocarbon Chain[J].Journal of Zhejiang Sci-Tech University,2017,37-38(自科6):202.
[5]彭丽,蔡凌云,郑旭明.ES纺粘无纺布表面活性剂亲水整理[J].浙江理工大学学报,2018,39-40(自科4):508.
 PENG Li,CAI Lingyun,ZHENG Xuming.Hydrophilic finishing of surfactant of ES spunbonded nonwoven fabric[J].Journal of Zhejiang Sci-Tech University,2018,39-40(自科6):508.

备注/Memo

备注/Memo:
收稿日期: 2015-11-06
基金项目: 国家自然科学基金项目(51133006);绍兴市科技计划项目(2014B70015)
作者简介: 张晋菲(1990-),女,山西运城人,硕士研究生,主要从事功能性纤维方面的研究
通信作者: 陈文兴,E-mail:wxchen@zstu.edu.cn
更新日期/Last Update: 2016-11-21