|本期目录/Table of Contents|

[1]李况,王秉,彭志勤,等.双配体荧光配合物的合成及其对苦味酸的选择性传感[J].浙江理工大学学报,2021,45-46(自科四):520-526.
 LI Kuang,WANG Bing,PENG Zhiqin,et al.Synthesis of fluorescent complexes with double ligands and its selective sensing of trinitrophenol[J].Journal of Zhejiang Sci-Tech University,2021,45-46(自科四):520-526.
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双配体荧光配合物的合成及其对苦味酸的选择性传感()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第45-46卷
期数:
2021年自科第四期
页码:
520-526
栏目:
出版日期:
2021-07-10

文章信息/Info

Title:
Synthesis of fluorescent complexes with double ligands and its selective sensing of trinitrophenol
文章编号:
1673-3851 (2021) 07-0520-07
作者:
李况王秉彭志勤万军民
浙江理工大学材料科学与工程学院,杭州 310018
Author(s):
LI Kuang WANG Bing PENG Zhiqin WAN Junmin
School of Materials Science & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
荧光传感硝基芳烃易爆物聚集诱导发光配合物卟啉
分类号:
O657-3
文献标志码:
A
摘要:
为提高对硝基芳烃易爆物的检测效率,选用具有聚集诱导发光效应的四齿有机配体四[4(4′羧基苯基)苯基]乙烯与二价锌离子(Zn 2+ )进行配位形成片层,再采用水热法,将具有吡啶基官能团的二齿有机配体5,15二(4吡啶基)10,20二苯基卟啉与Zn(Ⅱ)配位轴向桥联片层,构筑成一种新型的双配体荧光配合物ZnTP;并进一步以ZnTP材料为荧光探针应用于硝基芳烃易爆物的选择性传感中。结果表明:ZnTP材料具有良好的热稳定性,且苦味酸能使ZnTP材料发生瞬时荧光淬灭;ZnTP材料检测苦味酸的体系中加入其他硝基芳烃易爆物也不会影响该淬灭结果,ZnTP材料对苦味酸具有优异的选择性传感能力。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2021-02-18
网络出版日期:2021-03-30
基金项目:浙江省自然科学基金项目(LY13B030009)
作者简介:李况(1997-),女,江西萍乡人,硕士研究生,主要从事荧光检测易爆物方面的研究
通信作者:万军民,E-mail:wanjunmin@zstu.edu.cn
更新日期/Last Update: 2021-09-13