|本期目录/Table of Contents|

[1]兰娅星,赵彦英,薛佳丹.2-氨基-5-甲硫基-1,3,4-噻二唑的FT-IR,FT-Raman和共振拉曼光谱指认[J].浙江理工大学学报,2015,33-34(自科4):570-573.
　LAN Ya xing,ZHAO Yan ying,XUE Jia dan.The Identification of 2-Amino-5-(Methylthio)-1, 3, 4-Thiadiazole Through FT-IR, FT-Raman and Resonance Raman Spectra[J].Journal of Zhejiang Sci-Tech University,2015,33-34(自科4):570-573.
点击复制

2-氨基-5-甲硫基-1,3,4-噻二唑的FT-IR,FT-Raman和共振拉曼光谱指认()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第33-34卷
期数:
2015年自科4期
页码:
570-573
栏目:
出版日期:
2015-07-10

文章信息/Info

Title:
The Identification of 2-Amino-5-(Methylthio)-1, 3, 4-Thiadiazole Through FT-IR, FT-Raman and Resonance Raman Spectra
文章编号:
1673-3851 (2015) 05-0724-05
作者:
兰娅星;  赵彦英;  薛佳丹
浙江理工大学理学院化学系, 杭州 310018
Author(s):
LAN Yaxing;  ZHAO Yanying;  XUE Jiadan
Department of Chemistry, Zhenjiang Sci-Tech University, Hangzhou 310018, China
关键词:
2-氨基-5-甲硫基-1; 3; 4-噻二唑;  密度泛函理论计算;  FT-IR;  FT-Raman;  共振拉曼光谱
分类号:
O643.12
文献标志码:
A
摘要:
利用共振拉曼光谱技术以及密度泛函理论(DFT)计算对2-氨基-5-甲硫基-1,3,4-噻二唑(5-AMTT)在FranckCondon区域的光诱导激发态短时动力学进行了研究。通过实验获得了5-AMTT固体的FTIR和FTRaman光谱,并结合量子化学计算确认了5-AMTT的稳定构型。获得了5-AMTT在乙腈、甲醇和水溶剂中309.1 nm激发波长下的共振拉曼光谱图。共振拉曼光谱可以被指认为9个Frank Condon活性振动模的基频、倍频和它们的组合频,其中5-AMTT环上C-5N-4的伸缩振动、CH 3上C—H的振动以及NH-2的振动的基频、倍频和组合频占据了其主要吸收带共振拉曼光谱强度的绝大部分,表明5AMTT激发态结构动力学主要沿着这些反应坐标展开。

参考文献/References:

［1］ Zhang J H, He Y F, Gong Y S, et al. Modern Lubricating Oil and Fuel Additive［M］. Beijing: China Petrochemical Press, 1991, 135-143.
［2］ Li J, Ren T H. The tribochemical study of two triazine derivatives as additives in rapeseed oil［J］. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, 2008, 222(7): 917-923.
［3］ Shouji E, Buttry D A. An investigation of the effect of  pyridine derivatives on the oxidative polymerization process of 2, 5dimercapto1, 3, 4thiadiazole and its disulfide dimer［J］. The Journal of Physical Chemistry B, 1998, 102(8): 1444-1449.
［4］ Hassaneen H M, Shawali A S, Abdallah T A, et al. Synthesis and cycloaddition reactions of 4, 4dimethyl2, 6dioxocyclohexanethiocarboxamides with nitrilimines［J］. Arkivoc, 2014, 6: 155-169.
［5］ Gharu C P. Green and efficient microwave assisted synthesis of schiff bases and hydroxyl derivatives of 1, 3, 4thiadiazole containing Nmethyl piperazine moiety and their antimicrobial and antioxidant potential［J］. Arabian Journal of Chemistry. 2014, 7, 181-187.
［6］ Hu Y, Li C Y, Wang X M, et al. 1, 3, 4Thiadiazole: synthesis, reactions, and applications in medicinal, agricultural, and materials chemistry［J］. Chemical Reviews, 2014, 114(10), 5572-5610.
［7］ Alagawadi K R, Alegaon S G. Synthesis, characterization and antimicrobial activity evaluation of new 2, 4thiazolidinediones bearing imidazo［2, 1b］［1, 3, 4］ thiadiazole moiety［J］. Arabian Journal of Chemistry, 2011, 4(4): 465-472.
［8］ Sunil D, Isloor A M, Shetty P, et al. Synthesis, characterization, antioxidant, and anticancer studies of 6［3(4chlorophenyl)1Hpyrazol4yl］3［(2naphthyloxy) methyl］［1, 2, 4］ triazolo［3, 4b］［1, 3, 4］ thiadiazole in HepG2 cell lines［J］. Medicinal Chemistry Research, 2011, 20(7): 1074-1080.
［9］ Khan I, Ali S, Hameed S, et al. Synthesis, antioxidant activities and urease inhibition of some new 1, 2, 4triazole and 1, 3, 4thiadiazole derivatives［J］. European Journal of Medicinal Chemistry, 2010, 45(11): 5200-5207.
［10］ Hasui T, Matsunaga N, Ora T, et al. Identification of benzoxazin3one derivatives as novel, potent, and  selective nonsteroidal mineralocorticoid receptor antagonists［J］. Journal of Medicinal Chemistry, 2011, 54(24): 8616-8631.
［11］ Xu W M, Li S Z, He M, et al. Synthesis and bioactivities of novel thioether/sulfone derivatives containing 1, 2, 3thiadiazole and 1, 3, 4oxadiazole/thiadiazole moiety［J］. Bioorganic & Medicinal Chemistry Letters, 2013, 23(21): 5821-5824.
［12］ Zoumpoulakis P, Camoutsis C, Pairas G, et al. Synthesis of novel sulfonamide1, 2, 4triazoles, 1, 3, 4thiadiazoles and 1, 3, 4oxadiazoles, as potential antibacterial and antifungal agents. Biological evaluation and conformational analysis studies［J］. Bioorganic & Medicinal Chemistry, 2012, 20(4): 1569-1583.

相似文献/References:

[1]李星,张俊,李杨,等.3,4,5 三甲氧基苯乙酸的合成新工艺研究[J].浙江理工大学学报,2013,30(04):609.
　LI Xing,ZHANG Jun,LI Yang,et al.Research on New Synthetic Process of 3,4,5 trimethoxy phenylacetic Acid[J].Journal of Zhejiang Sci-Tech University,2013,30(自科4):609.
[2]庞素梅,赵彦英.2,5 二甲基 1,3,4 噻二唑激发态结构动力学的共振拉曼光谱研究[J].浙江理工大学学报,2017,37-38(自科1):127.
　PANG Sumei,ZHAO Yanying.Resonance Raman Spectroscopic Investigation of Excited State  Structural Dynamics of 2, 5 dimethyl 1, 3, 4 thiadiazole[J].Journal of Zhejiang Sci-Tech University,2017,37-38(自科4):127.
[3]葛肖瑜,崔灿.3,4,5-三羟基苯甲酸对钙钛矿薄膜质量和太阳能电池性能的影响[J].浙江理工大学学报,2022,47-48(自科一):31.
　GE Xiaoyu,CUI Can.Effect of 3,4,5-trihydroxybenzoic acid on the quality of perovskite film and the performance of solar cells[J].Journal of Zhejiang Sci-Tech University,2022,47-48(自科4):31.
[4]兰娅星,赵彦英,薛佳丹.2-氨基-5-甲硫基-1,3,4噻二唑的FT-IR,FT-Raman和共振拉曼光谱指认[J].浙江理工大学学报,2015,33-34(自科5):724.
　LAN Ya xing,ZHAO Yan ying,XUE Jia dan.The Identification of 2-Amino-5(Methylthio)-1, 3, 4-Thiadiazole Through FT-IR, FT-Raman and Resonance Raman Spectra[J].Journal of Zhejiang Sci-Tech University,2015,33-34(自科4):724.

备注/Memo

备注/Memo:
收稿日期： 2014-12-18
基金项目： 国家自然科学基金项目(21273202)
作者简介： 兰娅星(1986-),女,河北邯郸人,硕士研究生,主要从事物理化学方面的研究
通信作者： 赵彦英,E-mail:yyzhao@zstu.edu.cn
更新日期/Last Update: 2015-09-24