|本期目录/Table of Contents|

[1]王瑾,杜明亮,傅雅琴.高透光聚有机硅氧烷的合成及结构性能研究[J].浙江理工大学学报,2012,29(04):465-468.
　WANG Jin,DU Ming liang,FU Ya qin. Study on Preparation, Structure and Performance ofPolysiloxane with High Transparency[J].Journal of Zhejiang Sci-Tech University,2012,29(04):465-468.
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高透光聚有机硅氧烷的合成及结构性能研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第29卷
期数:
2012年04期
页码:
465-468
栏目:
(自科)纺织与服装工程
出版日期:
2012-08-28

文章信息/Info

Title:
 Study on Preparation, Structure and Performance ofPolysiloxane with High Transparency
文章编号:
16733851 (2012) 04046504
作者:
 王瑾;  杜明亮;  傅雅琴
 浙江理工大学先进纺织材料与制备技术教育部重点实验室, 杭州 310018
Author(s):
 WANG Jin;  DU Mingliang;  FU Yaqin
 The Key Laboratory of Advanced Textile Materials and Manufacturing Technology(Zhejiang SciTech University), Ministry of Education, Hangzhou 310018, China
关键词:
 ; 聚有机硅氧烷;  水解缩聚;  硅氢加成;  折光指数;  透明度
分类号:
TQ323.9
文献标志码:
A
摘要:
     通过硅氧烷水解缩聚制备具有乙烯基和氢基的聚有机硅氧烷预聚物，预聚物在铂催化剂的作用下经硅氢加成固化为具有高度交联结构的聚有机硅氧烷树脂。利用核磁共振、红外光谱、凝胶色谱等方法研究预聚物和聚有机硅氧烷树脂的结构与性能。结果表明：预聚物中成功引入硅乙烯基、苯基及硅氢基，分子量约为1 100 g/mol，折光指数超过1.52；聚有机硅氧烷树脂具有高苯基含量和三维网状结构，透光率超过99%，在可见光区域基本无吸收，具备优异的光学性能。

参考文献/References:

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［8］ Schmidt U I, Schrder B, Oechsner H. Influence of powder formation in a silane discharge on a\|Si∶H film growth monitored by in situ ellipsometry［J］. J Non\|Cryst Solids, 1993, 164\|166, Part 1: 127\|130.
［9］ Flipsen T. Design, synthesis and properties of new materials based on densely crosslinked polymers for polymer optical fiber and amplifier applications［M］. Wageningen: University of Groningen, 2000.
［10］Kuniyoshi M, Takahashi M, Tokuda Y, et al. Hydrolysis and polycondensation of acid\|catalyzed Phenyltriethoxysilane (PhTES)［J］. J Sol\|Gel Sci Techn, 2006, 39: 175\|183.
［11］ Engelhardt G, Mgi M, Lippmaa E. 29Si\|NMR\|spektroskopische untersuchungen an methyl\|und methyl\|phenyl\|siloxanen und ihre anwendung in der silikonanalytik［J］. J Organomet Chem, 1973, 54: 115\|122.
［12］ Menaa B, Takahashi M, Tokuda Y, et al. High optical quality spin\|coated polyphenylsiloxane glass thick films on polyethyleneterephtalate and silica substrates［J］. Mater Res Bull, 2006, 41: 1925\|1934.

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备注/Memo

备注/Memo:
 收稿日期： 2012-01-03
基金项目： 国家自然科学基金（50903072）
作者简介： 王瑾（1985-），女，安徽巢湖人，硕士研究生。主要从事有机硅树脂的研究。
通讯作者： 杜明亮，电子邮箱:du@zstu.edu.cn
更新日期/Last Update: