|本期目录/Table of Contents|

[1]王理超,孙海洋,祝成炎,等.环氧基硅烷偶联剂改性对 GF/PA6复合材料力学性能的影响[J].浙江理工大学学报,2026,55-56(自科六):784-794.
 WANG Lichao,SUN Haiyang,ZHU Chengyan,et al.Effect of epoxy-functional silane coupling agent modification on m echanical properties of GF/PA6composites[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科六):784-794.
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环氧基硅烷偶联剂改性对 GF/PA6复合材料力学性能的影响()

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
55-56
期数:
2026年自科第六期
页码:
784-794
栏目:
出版日期:
2026-11-10

文章信息/Info

Title:
Effect of epoxy-functional silane coupling agent modification on m echanical properties of GF/PA6composites
文章编号:
1673-3851(2026) 11-0784-11
作者:
王理超; 孙海洋; 祝成炎; 金肖克; 马雷雷;  田伟
浙江理工大学纺织科学与工程学院(国际丝绸学院)
Author(s):
WANG Lichao; SUN Haiyang; ZHU Chengyan; JIN Xiaoke; MA Leilei; TIAN Wei
School of Textile Science and Engineering(International Institute of Silk) ,Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
硅烷偶联剂; 改性处理; 玻璃纤维 ; 聚酰胺 6; 复合材料 ; 力学性能
分类号:
TB332
文献标志码:
A
摘要:
为探究硅烷偶联剂 KH560改性处理对玻璃纤维增强聚酰胺 6(GF/PA6)复合材料力学性能的影响 ,采用不同质量分数(0.5%~2.5%)的环氧基硅烷偶联剂 KH560对玻璃纤维(GF)织物进行表面改性;以改性前后的GF织物为增强体 ,聚酰胺 6(PA6)薄膜为基体 ,通过热压成型工艺制备 GF/PA6复合材料 ;借助红外光谱、接触角测试表征 GF织物表面的化学结构与润湿性 ,并利用X射线光电子能谱仪、万能强力仪、冲击试验机、扫描电镜及光学显微镜 ,分析复合材料的化学组成、力学性能及断裂形貌 。结果表明 :KH560能与 GF及 PA6发生界面化学反应 ,并改善 PA6熔体对 GF织物的润湿性;GF/PA6复合材料拉伸强度、弯曲强度及冲击强度随 KH560质量分数的增加呈先增后 减 趋 势 , 在 质 量 分 数 为 2.0%时 达 到 最 优 , 相 比 未 改 性 的 复 合 材 料 分 别 提 升 了 34.08%、28.00%和30.77% 。该研究为 GF/PA6复合材料的力学性能优化提供了实验依据和理论参考。

参考文献/References:

[1] Chen K, Jia M, Sun H, et al. Thermoplastic reaction injection pultrusion for continuous glass fiber-reinforced polyamide-6 composites [J]. Materials, 2019, 12 (3): 463.
[2] 王小庆,徐成明。碳纤维对聚酰胺复合材料力学性能和热稳定性的影响 [J]. 塑料科技,2025, 53 (10): 55-59. WANG X Q, XU C M. Effect of carbon fiber on mechanical properties and thermal stability of polyamide composites [J]. Plastics Science and Technology, 2025, 53 (10): 55-59.
[3] 冯冰涛,王晓珂,张萌,等。原位聚合法制备连续玻璃纤维增强尼龙 6 复合材料的改性和性能 [J]. 高分子材料科学与工程,2024, 40 (1): 25-33. FENG B T, WANG X K, ZHANG M, et al. Modification and properties of continuous glass fiber reinforced nylon 6 composites prepared by in-situ polymerization [J]. Polymer Materials Science & Engineering, 2024, 40 (1): 25-33.
[4] 赵智奎,戚栋明,王龙飞,等。玻璃纤维界面改性及其复合材料力学性能的研究进展 [J]. 纺织科学与工程学报,2023, 40 (3): 120-125, 138. ZHAO Z K, QI D M, WANG L F, et al. Research progress on interface modification of glass fiber and mechanical properties of its composites [J]. Journal of Textile Science and Engineering, 2023, 40 (3): 120-125, 138.
[5] Andrew J J, Srinivasan S M, Arockiarajan A, et al. Parameters influencing the impact response of fiber-reinforced polymer matrix composite materials: a critical review [J]. Composite Structures, 2019, 224: 111007.
[6] Gupta K, Fegade V, Kittur J, et al. A review on effect of cooling rate in fiber reinforced polymeric composites [J]. Proceedings of the AIP Conference Proceedings, 2022, 2393 (1): 020106.
[7] 廖俊杰,郭润杰,张敬嘉鸣,等。酸碱刻蚀和硅烷偶联剂改性对玄武岩纤维复合材料力学性能的影响 [J]. 塑料科技,2025, 53 (6): 100-104. LIAO J J, GUO R J, ZHANG J J M, et al. Effects of acid-base etching and silane coupling agent modification on mechanical properties of basalt fiber composites [J]. Plastics Science and Technology, 2025, 53 (6): 100-104.
[8] 孙鹏,金涛,田帅,等。硅烷偶联剂改性玻璃纤维增强 PA6 研究 [J]. 化工新型材料,2016, 44 (1): 205-207. SUN P, JIN T, TIAN S, et al. Study on glass fiber reinforced PA6 modified by silane coupling agent [J]. New Chemical Materials, 2016, 44 (1): 205-207.
[9] Zhu M, Lerum M Z, Chen W. How to prepare reproducible, homogeneous, and hydrolytically stable aminosilane-derived layers on silica [J]. Langmuir, 2012, 28 (1): 416-423.
[10] 王振彪,王琛琛,李刚,等. KH560 对碳纤维树脂基复合材料性能的影响 [J]. 辽宁化工,2023, 52 (9): 1271-1274. WANG Z B, WANG C C, LI G, et al. Effect of KH560 on properties of carbon fiber resin matrix composites [J]. Liaoning Chemical Industry, 2023, 52 (9): 1271-1274.
[11] 霍红宇,姚鑫,高亮,等。高性能连续纤维增强热塑性预浸料及复合材料制备工艺研究进展 [J]. 材料工程,2025, 53 (3): 44-53. HUO H Y, YAO X, GAO L, et al. Research progress on preparation technology of high-performance continuous fiber reinforced thermoplastic prepregs and composites [J]. Journal of Materials Engineering, 2025, 53 (3): 44-53.
[12] Hu J, Li F, Wang B, et al. A two-step combination strategy for significantly enhancing the interfacial adhesion of CF/PPS composites: the liquid-phase oxidation followed by grafting of silane coupling agent [J]. Composites Part B: Engineering, 2020, 191: 107966.
[13] Tong J, Guo S, Zhu H, et al. Ir-catalyzed reductive amination and transfer hydrogenation of diketones: access to β- and γ-amino alcohols [J]. RSC Advances, 2024, 14 (51): 38105-38109.
[14] Slapnik J, Lorber R, Pulko I, et al. Overprinting of TPU onto PA6 substrates: the influences of the interfacial area, surface roughness and processing parameters on the adhesion between components [J]. Polymers, 2024, 16 (5): 650.
[15] Zhou H, Liu H Y, Zhou H, et al. On adhesive properties of nano-silica/epoxy bonded single-lap joints [J]. Materials & Design, 2016, 95: 212-218.

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备注/Memo

备注/Memo:
收稿日期 : 2026-03-24 网络出版日期 : 2026-06-04作者简介 : 王理超(2000— ) ,男 ,湖南郴州人 ,硕士研究生 ,主要从事复合材料方面的研究。通信作者: 田 伟,E-mail:tianwei_zstu@zstu. edu. cn
更新日期/Last Update: 2026-11-09