|本期目录/Table of Contents|

[1]张雨,陶琳玲,吴明华,等.聚酰胺聚醚共聚型亲水整理剂的合成及其性能研究[J].浙江理工大学学报,2026,55-56(自科六):775-783.
　ZHANG Yu,TAO Linling,WU Minghua,et al.A study on synthesis and performance of a polyamide-polyether c opolymer hydrophilic finishing agent[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科六):775-783.
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聚酰胺聚醚共聚型亲水整理剂的合成及其性能研究()

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
55-56
期数:
2026年自科第六期
页码:
775-783
栏目:
出版日期:
2026-11-10

文章信息/Info

Title:
A study on synthesis and performance of a polyamide-polyether c opolymer hydrophilic finishing agent
文章编号:
1673-3851(2026) 11-0775-09
作者:
张雨 ; 陶琳玲 ; 吴明华 ; 董倩倩
1. 浙江理工大学 ,a. 纺织科学与工程学院(国际丝绸学院)
Author(s):
ZHANG Yu ; TAO Linling ; WU Minghua ; DONG Qianqian
1a. College of Textile Science and Engineering(International Institute of Silk) ; 1b. Engineering Research Center for Eco-Dyeing& Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Zhejiang Sci-Tech University Tongxiang Research Institute Co. , Ltd. , Tongxiang314500, China;3. Zhejiang Kaide Chemical Co. , Ltd. , Shaoxing312300, China
关键词:
亲水整理剂 ; 聚酰胺聚醚共聚物 ; 锦纶织物 ; 耐水洗牢度
分类号:
TS195.2
文献标志码:
A
摘要:
为提升锦纶织物的亲水性和耐水洗性 ,通过二步法制备了聚酰胺聚醚共聚型亲水整理剂(PAPG) 。首先 ,将丁二酸酐(SA)和聚乙二醇 (PEG)在催化剂亚磷酸(H3PO3)的作用下进行酯化反应 ,合成端羧基聚醚中间体(CT-PEG) ;然后 ,加入己二酸(AA)和己二胺(HDA) ,在催化剂次磷酸钠(NaH2PO2)的作用下进行缩聚反应 ,制得亲水整理剂 PAPG。通过 FTIR和1 H NMR对 PAPG的结构进行表征分析 ;通过测定整理织物的毛效高度和水洗毛效保留率 ,探究PEG相对分子质量、原料投入比、催化剂 NaH2PO2 用量以及缩聚反应温度和时间对整理锦纶织物亲水性和耐水洗性的影响 ,优化合成工艺条件 ;通过测定 GPC、表面张力和浊点 ,探究PAPG的相对分子质量和物化性能 。结果表明 :PAPG分子为聚酰胺聚醚结构;PAPG优化合成工艺条件为 PEG相对分子质量 800,n(AA) ∶ n(HDA) ∶n(CT-PEG)投入比 0.6∶1.6∶1.0,催化剂 NaH2PO2 质量分数 2% ,反应温度 240℃ ,时间 2.5 h;PAPG的数均相对分子质量为2786;PAPG水溶液的表面张力为 49.21 mN/m, 浊点为 62℃;经 PAPG整理锦纶织物的毛效高度为 8.2 cm/5min,10次洗涤后毛效保留率在 90%以上 。研究表明 PAPG具有良好的亲水性和耐水洗性 , 可为开发锦纶织物亲水整理剂提供参考。

参考文献/References:

[1] Zhang W, Li J X, Tang R C, et al. Hydrophilic and antibacterial surface functionalization of polyamide fabric by coating with polylysine biomolecule [J]. Progress in Organic Coatings, 2020, 142: 105571.
[2] 杨乔伟。聚酰胺 6 在我国市场发展的前景分析 [J]. 中国石油和化工标准与质量，2025, 45 (11): 145-147. YANG Q W. Prospect analysis of polyamide 6 in China’s market [J]. China Petroleum and Chemical Standard and Quality, 2025, 45 (11): 145-147.
[3] Lee J Y, Oh B O, Cho H H, et al. Synthesis of hydrophilic polyamide copolymers based on nylon 6 and nylon 46 [J]. Fibers and Polymers, 2019, 20 (11): 2227-2235.
[4] Li L, Liu S, Liu R, et al. Preparation and characterization of hydrophilic wetting-modified polyamide fibers [J]. Advances in Polymer Technology, 2020, 2020: 8475497.
[5] 魏宇晖，李秋颖，宋凯利，等。锦纶织物防水 / 亲水异面整理工艺研究 [J]. 现代纺织技术，2020, 28 (2): 65-69. WEI Y H, LI Q Y, SONG K L, et al. Research on one-side waterproof and one-side hydrophilic finishing of polyamide fabric [J]. Advanced Textile Technology, 2020, 28 (2): 65-69.
[6] 伍建国，汪南方，吕爱霞。锦纶耐洗亲水整理剂的应用性能 [J]. 印染，2023, 49 (1): 29-33. WU J G, WANG N F, LÜ A X. Application performance of wash-resistant hydrophilic finishing agent for polyamide fabrics [J]. Dyeing & Finishing, 2023, 49 (1): 29-33.
[7] 程金放，吴明华，刘彦杰，等。氨基聚醚聚硅氧烷嵌段型聚合物的合成及应用 [J]. 浙江理工大学学报，2013, 30 (3): 302-307. CHENG J F, WU M H, LIU Y J, et al. Synthesis and application of amino polyether polysiloxane block copolymer [J]. Journal of Zhejiang Sci-Tech University, 2013, 30 (3): 302-307.
[8] Zhang Q, Pei L, Yu S, et al. Influence of MA-AA copolymer modification on dye affinity and industrial feasibility of polyurethane reactive dyeing [J]. Polymer, 2026, 351: 129847.
[9] Kuang X M, Su M R, Wang L, et al. Study on recycled polyester/nylon/spandex modified by LDPE and LLDPE [J]. ChemistrySelect, 2025, 10 (5): e202401451.
[10] He C, Mou W, Zhu J, et al. TPU-g-MAH enhanced polyester/polyether TPU blends for water-resistant cotton fabric bonding [J]. Polymer Engineering & Science, 2026, 66 (4): 2978-2996.
[11] Deng C Y, Jin J C, Zhang H, et al. Synthesis of a reactive cationic/nonionic waterborne polyurethane dye fixative and its application performance on viscose fiber fabrics [J]. Polymers, 2024, 16 (1): 89.
[12] 杨林波，越誉钧，葛文凤，等。一种超亲水有机硅柔软整理剂的合成与应用 [J]. 印染助剂，2025, 42 (10): 23-28. YANG L B, YUE Y J, GE W F, et al. Synthesis and application of superhydrophilic silicone softener [J]. Textile Auxiliaries, 2025, 42 (10): 23-28.
[13] 张保根，吴明华，程金放，等。新型聚酰胺纤维亲水整理剂 PPAG 合成及其应用研究 [J]. 印染助剂，2012, 29 (6): 14-17, 21. ZHANG B G, WU M H, CHENG J F, et al. Synthesis and application of a novel hydrophilic finishing agent PPAG for polyamide fibers [J]. Textile Auxiliaries, 2012, 29 (6): 14-17, 21.
[14] 赵甘林，杨涛，蒲泽佳，等。锦纶用交联型吸湿排汗整理剂的合成及应用 [J]. 印染助剂，2016, 33 (7): 26-30, 40. ZHAO G L, YANG T, PU Z J, et al. Synthesis and application of crosslinked moisture-absorbing and sweat-releasing finishing agent for polyamide fabrics [J]. Textile Auxiliaries, 2016, 33 (7): 26-30, 40.
[15] 徐山山，吴德举，张惠萍。亲水柔软整理剂的合成与应用 [J]. 印染助剂，2023, 40 (11): 26-28, 48. XU S S, WU D J, ZHANG H P. Synthesis and application of hydrophilic soft finishing agent [J]. Textile Auxiliaries, 2023, 40 (11): 26-28, 48.
[16] 胡晓园，吴夏琼，董倩倩，等。锦纶用聚醚改性聚酰胺亲水整理剂的合成及应用性能 [J]. 印染，2025, 51 (7): 44-48. HU X Y, WU X Q, DONG Q Q, et al. Synthesis and application performance of polyether-modified polyamide hydrophilic finishing agent for polyamide fabrics [J]. Dyeing & Finishing, 2025, 51 (7): 44-48.
[17] 缪凯伦。聚酰胺聚醚嵌段共聚物的合成及其在锦纶织物亲水整理中的应用 [D]. 杭州：浙江理工大学，2018: 31-44. MIAO K L. Synthesis of polyamide-polyether block copolymer and its application in hydrophilic finishing of polyamide fabrics [D]. Hangzhou: Zhejiang Sci-Tech University, 2018: 31-44.
[18] Pielichowski K, Flejtuch K. Differential scanning calorimetry studies on poly (ethylene glycol) with different molecular weights for thermal energy storage materials [J]. Polymers for Advanced Technologies, 2002, 13 (10/11/12): 690-696.
[19] 叶冲，莫雅伦，刘奔，等。拉曼光谱法研究聚乙二醇的非等温结晶及其相变行为 [J]. 塑料工业，2018, 46 (5): 116-120. YE C, MO Y L, LIU B, et al. Non-isothermal crystallization and phase transition behavior of polyethylene glycol studied by Raman spectroscopy [J]. China Plastics Industry, 2018, 46 (5): 116-120.
[20] 霍丽，李华. PA1212-b-PEG 嵌段共聚物的组成对结晶和熔融行为的影响 [J]. 化工新型材料，2012, 40 (3): 88-90. HUO L, LI H. Effect of composition on crystallization and melting behavior of PA1212-b-PEG block copolymer [J]. New Chemical Materials, 2012, 40 (3): 88-90.
[21] Sun Y, Zhou X. Preparation and application of a novel durable hydrophilic finishing agent for polyamide fabric [J]. The Journal of the Textile Institute, 2019, 110 (9): 1300-1306.

备注/Memo

备注/Memo:
基金项目 : 浙江理工大学-桐乡研究院产业化项目(TYY202308)收稿日期 : 2026-03-25 网络出版日期 : 2026-06-04
作者简介 : 张 雨 (2002— ) ,女 ,河南周口人 ,硕士研究生 ,主要从事生态染整技术方面的研究。通信作者: 吴明华,E-mail:wmh@zstu. edu. cn
更新日期/Last Update: 2026-11-09