|本期目录/Table of Contents|

[1]谢鹏杰,顾挺业,陈涛,等.液体分散染料免水洗印花用高锁色黏合剂的制备及应用[J].浙江理工大学学报,2026,55-56(自科五):573-581.
　XIEPengjie,GUTingye,CHEN Tao,et al.Preparation and application of a high color-retention binder for wash-free printing with liquid disperse dyes[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科五):573-581.
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液体分散染料免水洗印花用高锁色黏合剂的制备及应用()

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
55-56
期数:
2026年自科第五期
页码:
573-581
栏目:
出版日期:
2026-09-20

文章信息/Info

Title:
Preparation and application of a high color-retention binder for wash-free printing with liquid disperse dyes
文章编号:
1673-3851(2026) 09-0573-09
作者:
谢鹏杰 ; 顾挺业 ; 陈涛 ; 戚栋明 ; 崔志华
1. 浙江理工大学绿色低碳染整技术浙江省工程研究中心 ,杭州 310018;2. 浙江省现代纺织技术创新中心 ,浙江绍兴 312030
Author(s):
XIEPengjie ; GUTingye; CHEN Tao; QIDongming ; CUIZhihua
1. Zhejiang Provincial Engineering Research Center for Green and Low-Carbon Dyeing& Finishing,Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Zhejiang Provincial Innovation Center of Advanced Textile Technology, Shaoxing312030, China
关键词:
液体分散染料 ; 免水洗印花 ;  氟硅改性聚丙烯酸酯; 色牢度 ;  紫外防护
分类号:
TS195.644
文献标志码:
A
摘要:
针对传统分散染料印花水洗能耗高、废水多 , 以及现有免水洗聚丙烯酸酯黏合剂耐水性不足且缺乏紫外屏蔽能力等问题 , 以 自制的端乙烯基含氟聚硅氧烷(DVFS)和丙烯腈(AN)为功能单体 ,采用细乳液聚合法制备氟硅改性聚丙烯酸酯(F/Si-PA)乳液 ,利用 DVFS的低表面能特性在成膜时向界面迁移以提升疏水性 , 同时利用 AN中氰基的强极性与紫外吸收能力增强胶膜内聚力并抑制紫外线对染料分子的破坏 ;通过 FT-IR、1 H NMR和 XPS表征 F/Si-PA的化学结构 ,并将其应用于液体分散染料免水洗印花场景 ; 系统评估乳液性能、胶膜耐水性、紫外阻隔性能及 F/Si-PA乳液在免水洗印花中的应用效果 。表征结果表明 : 氟硅链段与氰基成功引入 ,Si与 F元素在胶膜表面显著富集 ;最优配方下乳液平均粒径为 45 nm,胶膜吸水率和质量溶胀度分别降至 38.86%和 16.20% , 紫外防护系数 (UPF)达 105.48。应用结果显示 :印花织物的干/湿摩擦色牢度分别达到 4~ 5级和 3~4级 , 耐水洗褪色率低至1.1% ,且 100h 日晒褪色率仅为 1.9% ,综合性能显著优于市售主流黏合剂 MCH-206。该研究表明 , 氟硅链段与氰基的协同改性策略有效提升了胶膜的疏水致密性与紫外防护能力 , 满足液体分散染料免水洗印花体系的高锁色需求。

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相似文献/References:

[1]余夏杰,黄俊峰,顾挺业,等.高强度液体分散染料免水洗印花色浆复配体系研究[J].浙江理工大学学报,2026,55-56(自科五):582.
　YU Xiajie,HUANG Junfeng,GU Tingye,et al.Research on the compounding system of high-intensity liquid disperse dyes wash-free printing color paste[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科五):582.

备注/Memo

备注/Memo:
基金项目 : 国家自然科学基金项目(52273216)收稿日期 : 2026-01-16 网络出版日期 : 2026-04-29
作者简介 : 谢鹏杰(2000— ) ,男 ,河南信阳人 ,硕士研究生 ,主要从事印染助剂方面的研究。通信作者: 陈 涛,E-mail:tao. chen@zstu. edu. cn
更新日期/Last Update: 2026-09-20