|本期目录/Table of Contents|

[1]郑智建,张晶晶,孔祥东,等.仿生矿化聚乙烯醇复合膜材料的制备及其力学性能分析[J].浙江理工大学学报,2025,53-54(自科二):175-184.
　ZHENG Zhijian,ZHANG Jingjing,KONG Xiangdong,et al.Preparation and mechanical property analysis of a biomimetic mineralized polyvinyl alcohol composite film[J].Journal of Zhejiang Sci-Tech University,2025,53-54(自科二):175-184.
点击复制

仿生矿化聚乙烯醇复合膜材料的制备及其力学性能分析()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第53-54卷
期数:
2025年自科第二期
页码:
175-184
栏目:
出版日期:
2025-03-10

文章信息/Info

Title:
Preparation and mechanical property analysis of a biomimetic mineralized polyvinyl alcohol composite film
文章编号:
1673-3851 (2025) 03-0175-10
作者:
郑智建; 张晶晶; 孔祥东; 赵瑞波
浙江理工大学材料科学与工程学院，杭州 310018
Author(s):
ZHENG Zhijian;  ZHANG Jingjing;  KONG Xiangdong;  ZHAO Ruibo
School of Materials Science & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
仿生矿化; 有机无机共聚; 聚乙烯醇; 羧甲基壳聚糖; 磷酸钙寡聚体; 力学性能
分类号:
TB332
文献标志码:
A
摘要:
为了提升聚乙烯醇（Polyvinyl alcohol，PVA）膜材料的力学性能，采用仿生矿化策略引入羧甲基壳聚糖（Carboxymethyl chitosan，CMC）和磷酸钙寡聚体（Calcium phosphate oligomer，CPO），通过有机无机共聚制备新型PVA复合膜材料（PVA/CMC/CPO films，PCC）；对PCC膜的形貌、亲疏水性、结晶性、热稳定性、流变性以及力学性能等进行表征，并分析CPO含量对PCC膜材料性质的影响。结果表明：PVA、CMC可诱导CPO矿化形成羟基磷灰石（Hydroxyapatite, HAP）纤维，形成有机无机PVA复合膜材料，有效提高了PAV、CMC和CPO在膜材料内的均匀分布，提高了PCC膜的疏水性、热稳定性，并维持其良好的光透过率（85.3%）；掺入24% CPO的PCC膜材料弹性模量可达33.1 MPa，断裂伸长率可达823%。该研究制备的PVA复合膜材料具有良好的力学性能，在功能材料领域具有良好的应用前景。

参考文献/References:

［1］Tak H Y, Yun Y H, Lee C M, et al. Sulindac imprinted mungbean starch/PVA biomaterial films as a transdermal drug delivery patch［J］. Carbohydrate Polymers, 2019, 208: 261-268.
［2］Motasadizadeh H, Azizi S, Shaabani A, et al. Development of PVA/chitosan-g-poly (N-vinyl imidazole)/TiO 2/curcumin nanofibers as high-performance wound dressing［J］. Carbohydrate Polymers, 2022, 296: 119956.
［3］Ismayati M, Fatah N A N, Ernawati E E, et al. Antioxidant and UV-blocking activity of PVA/tannin-based bioplastics in food packaging application［J］. International Journal of Biological Macromolecules, 2024, 257(Pt 2): 128332.
［4］Worku L A, Tadesse M G, Bachheti A, et al. Experimental investigations on PVA/chitosan and PVA/chitin films for active food packaging using Oxytenanthera abyssinica lignin nanoparticles and its UV-shielding, antimicrobial, and antiradical effects［J］. International Journal of Biological Macromolecules, 2024, 254(Pt 1): 127644.
［5］Yang Q, Guo J, Zhang S, et al. Improved biomedical bioactivity of polyvinyl alcohol/polyethylene oxide composite system-based nanofiber membranes via incorporating Antarctic krill protein［J］. European Polymer Journal, 2023, 187: 111888.
［6］Müller L, Rosenbaum C, Rump A, et al. Determination of mucoadhesion of polyvinyl alcohol films to human intestinal tissue ［J］. Pharmaceutics, 2023, 15(6): 1740.
［7］Wang Z, Yan F, Pei H C, et al. Antibacterial and environmentally friendly chitosan/polyvinyl alcohol blend membranes for air filtration ［J］. Carbohydrate Polymers, 2018, 198: 241-248.
［8］Huang D J, Wang W B, Xu J X, et al. Mechanical and water resistance properties of chitosan/poly(vinyl alcohol) films reinforced with attapulgite dispersed by high-pressure homogenization［J］. Chemical Engineering Journal, 2012, 210: 166-172.
［9］Caz n P, Velazquez G, V zquez M. Novel composite films from regenerated cellulose-glycerol-polyvinyl alcohol: Mechanical and barrier properties［J］. Food Hydrocolloids, 2019, 89: 481-491.
［10］Castro J M, Montalbn M G, Martínez-Prez N, et al. Thermoplastic starch/polyvinyl alcohol blends modification by citric acid-glycerol polyesters［J］. International Journal of Biological Macromolecules, 2023, 244: 125478.

相似文献/References:

[1]陈思颖,谢番,赵瑞波,等.仿生矿化透明质酸钠复合材料的制备及其性能分析[J].浙江理工大学学报,2024,51-52(自科三):292.
　CHEN Siying,XIE Fan,ZHAO Ruibo,et al.Preparation of biomimetic mineralized sodium hyaluronate composites and the analysis of their properties[J].Journal of Zhejiang Sci-Tech University,2024,51-52(自科二):292.

备注/Memo

备注/Memo:
收稿日期： 2024-06-10
网络出版日期:2024-09-13
基金项目： 浙江省自然科学基金项目（LZ24E020002）；国家自然科学基金项目（51902289）
作者简介： 郑智建（1999—），男，福建仙游人，硕士研究生，主要从事生物医用材料方面的研究
通信作者： 赵瑞波，E-mail：rzhao@zstu.edu.cn
更新日期/Last Update: 2025-03-06