|本期目录/Table of Contents|

[1]叶宸硕,许铭冬,唐凌枫,等.钙钛矿相PbTiO 3 CdS微米片复合光催化剂的制备及其分解水产氢性能研究[J].浙江理工大学学报,2024,51-52(自科五):588-597.
　YE Chenshuo,XU Mingdong,TANG Lingfeng,et al.Study on the preparation of perovskite phase PbTiO 3 CdS microplate composite photocatalysts and performance of  their H 2 generation via water splitting[J].Journal of Zhejiang Sci-Tech University,2024,51-52(自科五):588-597.
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钙钛矿相PbTiO 3 CdS微米片复合光催化剂的制备及其分解水产氢性能研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第51-52卷
期数:
2024年自科第五期
页码:
588-597
栏目:
出版日期:
2024-09-20

文章信息/Info

Title:
Study on the preparation of perovskite phase PbTiO 3 CdS microplate composite photocatalysts and performance of  their H 2 generation via water splitting
作者:
叶宸硕; 许铭冬; 唐凌枫; 高文森; 朱敏; 尹思敏
浙江理工大学机械工程学院，杭州 310018
Author(s):
YE Chenshuo;  XU Mingdong;  TANG Lingfeng;  GAO Wensen;  ZHU Min;  YIN Simin
School of Mechanical Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
钙钛矿相PbTiO 3; CdS; 光催化; 水分解; 产氢
分类号:
TB34
文献标志码:
A
摘要:
为实现钙钛矿基半导体复合材料的高效光解水产氢，以钙钛矿相钛酸铅（PbTiO 3，PTO）微米片为衬底，采用水热法制备钙钛矿相钛酸铅硫化镉（PTO CdS）微米片复合材料。探究水热温度和CdS负载量对复合材料的形貌及物相的影响；通过TEM、XPS及UV Vis对复合材料的微结构、表面化学状态和光吸收特性进行表征；通过光解水产氢实验对复合材料的光催化活性进行测定和分析。结果表明：水热条件下，钙钛矿相PTO微米片对CdS的生长具有显著调控作用，与单独生长时尺寸约3 μm的枝杈晶形貌不同，PTO CdS微米片复合材料中的CdS为三角形纳米颗粒，尺寸约50 nm，均匀分散地生长在PTO微米片表面，且PTO与CdS之间界面清晰；水热温度和CdS负载量对复合材料的形貌和物相影响显著，水热温度为160 ℃、CdS负载量为6%时制备的PTO CdS微米片复合材料尺寸均一，负载均匀，纯度和结晶度良好；PTO CdS微米片复合材料在模拟太阳光下表现出光催化分解水产氢特性，其中PTO CdS 6%的产氢速率达到141.45 μmol/h/g，是PTO微米片产氢效率的17倍，是CdS枝杈晶产氢效率的53倍。该研究为高效钙钛矿基半导体复合光催化剂的设计提供了思路。

参考文献/References:

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相似文献/References:

[1]孟海丽,胡海华,沈洪磊,等. CdS空心球的制备及其光催化性能[J].浙江理工大学学报,2013,30(01):114.
　MENG Hai li,HU Hai hua,SHEN Hong lei,et al. Synthesis and Photocatalytic Activity of CdS Hollow Nanospheres[J].Journal of Zhejiang Sci-Tech University,2013,30(自科五):114.
[2]许铭冬,李文强,刘顺,等.PbTiO3-CdS纳米复合材料的制备及其微结构和光催化性能[J].浙江理工大学学报,2022,47-48(自科三):340.
　XU Mingdong,LI Wenqiang,LIU Shun,et al.Preparation of PbTiO3 CdS nano composite material and its  microstructure and photocatalytic property[J].Journal of Zhejiang Sci-Tech University,2022,47-48(自科五):340.

备注/Memo

备注/Memo:
收稿日期： 2024-01-12
网络出版日期：2024-04-12
基金项目： 国家自然科学基金项目(51602286)；浙江省自然科学基金项目(LY19E020015)
作者简介： 叶宸硕(1996—)，男，山东临沂人，硕士研究生，主要从事钙钛矿材料方面研究
通信作者： 尹思敏，E-mail: yinsm@zstu.edu.cn
更新日期/Last Update: 2024-09-18