|本期目录/Table of Contents|

[1]龚文丽,丁雁鸿,张晨一,等.超分子结构纤维素基吸附剂对水体中钴离子的去除[J].浙江理工大学学报,2021,45-46(自科五):604-611.
　GONG Wenli,DING Yanhong,ZHANG Chenyi,et al.Removal of cobalt ions from water by cellulosebased adsorbents with supramolecular structure[J].Journal of Zhejiang Sci-Tech University,2021,45-46(自科五):604-611.
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超分子结构纤维素基吸附剂对水体中钴离子的去除()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第45-46卷
期数:
2021年自科第五期
页码:
604-611
栏目:
出版日期:
2021-09-10

文章信息/Info

Title:
Removal of cobalt ions from water by cellulosebased adsorbents with supramolecular structure
文章编号:
1673-3851 (2021) 09-0604-08
作者:
龚文丽; 丁雁鸿; 张晨一; 刘琳; 姚菊明
浙江理工大学材料科学与工程学院，杭州 310018
Author(s):
GONG Wenli;  DING Yanhong;  ZHANG Chenyi;  LIU Lin;  YAO Juming
School of Materials Science & Engineering, Zhejiang Sci-Tech  University, Hangzhou Zhejiang, 310018
关键词:
超分子结构; 纤维素; 钴离子去除; 吸附; 静电相互作用; 配位络合
分类号:
X524
文献标志码:
A
摘要:
以纤维素为原料，采用高碘酸钠氧化后接枝支化聚乙烯亚胺，制备超分子结构纤维素基吸附剂（Supramolecular aminofunctionalized cellulose，SAC），并分析SAC去除Co 2+离子的能力，并通过FTIR、EDS、吸附动力学和吸附等温线模型探究其去除机理。结果表明：SAC能快速去除Co 2+离子，在10 min内达到吸附平衡；吸附容量随着pH值的增加而增加，吸附效率随着温度的增加而降低；SAC对Co 2+离子的吸附是一个自发的放热过程，符合伪二级吸附动力学和Langmuir等温吸附模型，SAC对Co 2+最大吸附容量为52-63 mg/g；SAC对Co 2+离子的高效去除效率是静电作用、配位络合及离子交换共同作用。为水体中Co 2+离子的去除提供了一种新方法。

参考文献/References:

［1］ Maity D, Raj A, Karthigeyan D, et al. Reactionbased probes for Co(II) and Cu(I) with dual output modes: fluorescence live cell imaging［J］. RSC Advances, 2013, 3(37): 16788-16794.
［2］ AlHabsi K, Johnson E H, Kadim I T, et al. Effects of low concentrations of dietary cobalt on liveweight gains, haematology, serum vitamin B12 and biochemistry of omani goats［J］. The Veterinary Journal, 2007, 173(1): 131-137.
［3］ Leyssens L, Vinck B, van der Straeten C, et al. Cobalt toxicity in humans：A review of the potential sources and systemic health effects［J］. Toxicology, 2017, 387(15): 43-56.
［4］ Vashisht D, Kaur K, Jukaria R, et al. Colorimetric chemosensor based on coumarin skeleton for selective naked eye detection of cobalt (II) ion in near aqueous medium［J］. Sensors and Actuators B: Chemical, 2019, 280: 219-226.
［5］ Upadhyay S, Singh A, Sinha R, et al. Colorimetric chemosensors for dmetal ions: A review in the past, present and future prospect［J］. Journal of Molecular Structure, 2019, 1193: 89-102.
［6］ Wang J P, Chen Y Z, Ge X W, et al. Gamma radiationinduced grafting of a cationic monomer onto chitosan as a occulant［J］. Chemosphere, 2007, 66: 1752-1757.
［7］ Michel C, Barre Y, De Windt L, et al. Ion exchange and structural properties of a new cyanoferrate mesoporous silica material for Cs removal from natural saline waters［J］. Journal of Environmental Chemical Engineering, 2017, 5: 810-817.
［8］ 高峰, 李明, 林力,等. 膜技术在放射性废水处理中的应用及展望［J］. 科技与创新, 2018, 17: 108-109.
［9］ 陈选, 梁军龙, 张梅飞, 等. 纤维素基絮凝材料的制备及其絮凝性能研究［J］. 浙江理工大学学报（自然科学版）, 2018, 39(5): 545-550.
［10］ Chen Y W, Wang J L. Removal of radionuclide Sr (II) ions from aqueous solution using synthesized magnetic chitosan beads［J］. Nuclear Engineering and Design, 2012, 242: 445-451.

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备注/Memo

备注/Memo:
收稿日期：2021-01-25
网络出版日期：2021-03-31
基金项目：国家自然科学基金项目（51672251）
作者简介：龚文丽（1995-），女，南昌人，硕士研究生，主要从事纤维素基功能材料方面的研究
通信作者：刘琳，E-mail：liulin@zstu.edu.cn
更新日期/Last Update: 2021-09-16