[1]王明乾,易玲敏,李静,等.涂层厚度对氟硅与甲基丙烯酸甲酯嵌段共聚物表面微观形貌和性质的影响[J].浙江理工大学学报,2017,37-38(自科1):31-34.
WANG Mingqian,YI Lingmin,LI Jing,et al.The Influence of Film Thickness on Surface Microtopography and Properties of Block Copolymers of Fluorosilicone and Methyl Methacrylate[J].Journal of Zhejiang Sci-Tech University,2017,37-38(自科1):31-34.
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涂层厚度对氟硅与甲基丙烯酸甲酯嵌段共聚物表面微观形貌和性质的影响(
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WANG Mingqian,YI Lingmin,LI Jing,et al.The Influence of Film Thickness on Surface Microtopography and Properties of Block Copolymers of Fluorosilicone and Methyl Methacrylate[J].Journal of Zhejiang Sci-Tech University,2017,37-38(自科1):31-34.
)浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]
- 卷:
- 第37-38卷
- 期数:
- 2017年自科1期
- 页码:
- 31-34
- 栏目:
- 出版日期:
- 2017-01-10
文章信息/Info
- Title:
- The Influence of Film Thickness on Surface Microtopography and Properties of Block Copolymers of Fluorosilicone and Methyl Methacrylate
- 文章编号:
- 1673-3851 (2017) 01-0031-04
- 分类号:
- O634.4
- 文献标志码:
- A
- 摘要:
- 将不同组成的氟硅与甲基丙烯酸甲酯两嵌段共聚物配制成溶液，经旋涂、退火处理后得到不同厚度的聚合物涂层。采用视频接触角张力仪（CAM）、原子力显微镜（AFM）和X射线光电子能谱仪（XPS）研究嵌段共聚物涂层的疏水性能、表面形貌以及化学组成随涂层厚度的变化情况。结果表明：随着涂层厚度的增加，涂层表面对水、甲酰胺、二碘甲烷的接触角逐渐增大，并且聚合物涂层表面氟元素含量逐渐上升。
参考文献/References:
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［2］ ROACH P, SHIRTCLIFFE N J, NEWTON M I. Progess in superhydrophobic surface development［J］. Soft Matter, 2008, 4(2)：224-240.
［3］ 成西涛,李稳宏,黄方方,等.氟硅三嵌段聚合物的合成及其表面性能［J］.材料导报,2016,30(6)：48-51.
［4］ 朱冠南，孙建平，任强,等.甲基丙烯酸环氧树脂 b 甲基丙烯酸十二氟庚酯嵌段共聚物的合成及其在疏水中的应用［J］.高分子材料科学与工程,2016,32(4)：11-16.
［5］ OZCAM A E, SPONTAK R J, GENZER J. Toward the development of a versatile functionalized silicone coating［J］. ACS Applied Materials & Interfaces,2014,6(24)：22544-22552.
［6］ YILGOR E, YILGOR I. Silicone containing copolymers：synthesis, properties and applications［J］.Progress in Polymer Science . 2014，39,1165-1195.
［7］ YI L, HUANG C, ZHOU W. Synthesis, surface properties and morphologies of poly［methyl(3,3,3tri?uoropropyl)siloxane］ b polystyrene b poly(tertbutyl acrylate) triblock copolymers by a combination of anionic ROP and ATRP［J］. Journal of Polymer Science Part A：Polymer Chemistry,2012,50(9)：1728-1739.
［8］ YI L, MENG X, TIAN X, et al. Wettability of electrospun films of microphaseseparated block copolymers with 3, 3, 3trifluoropropyl substituted siloxane segments［J］. The Journal of Physical Chemistry C,2014,118(46)：26671-26682.
［9］ TIAN X, YI L, MENG X, et al. Superhydrophobic surfaces of electrospun block copolymer fibers with low content of fluorosilicones［J］. Applied Surface Science,2014,307：566-575.
［10］ LI Q, YAN Y, YU M, et al. Synthesis of polymeric fluorinated solgel precursor for fabrication of superhydrophobic coating［J］. Applied Surface Science,2016,367：101-108.
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备注/Memo
- 备注/Memo:
-
收稿日期： 2016-06-01
网络出版日期： 2017-01-03
基金项目： 国家自然科学基金项目（21276243）
作者简介： 王明乾（1993-），男，安徽阜阳人，硕士研究生，主要从事氟硅高分子材料的方面研究
通信作者： 易玲敏，教授，E-mail: lmyi@zstu.edu.cn
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