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[1]曹益宁a,崔志华a,b,等. 吡啶酮型苯并三唑紫外线吸收剂的合成与光谱特性[J].浙江理工大学学报,2011,28(06):846-849.
　CAO Yi ninga,CUI Zhi huaa,b,et al. Synthesis and Spectral Properties of Pyridone Type Benzotriazole UV Absorber[J].Journal of Zhejiang Sci-Tech University,2011,28(06):846-849.
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 吡啶酮型苯并三唑紫外线吸收剂的合成与光谱特性()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第28卷
期数:
2011年06期
页码:
846-849
栏目:
(自科)纺织与服装工程
出版日期:
2011-12-30

文章信息/Info

Title:
 Synthesis and Spectral Properties of Pyridone Type Benzotriazole UV Absorber
文章编号:
16733851 (2011) 06084604
作者:
 曹益宁a;  崔志华a; b;  陈维国a; b;  郭江潮a
 浙江理工大学, a. 先进纺织材料与制备技术教育部重点实验室; b. 生态染整技术教育部工程研究中心， 杭州 310018
Author(s):
 CAO Yininga;  CUI Zhihuaa; b;  CHEN Weiguoa; b;  GUO Jiangchaoa
Zhejiang SciTech University, a. The Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education; b. The Engineering Research Center for EcoDyeing & Finishing of Textiles, Ministry of Education, Hangzhou 310018, China
关键词:
 ; 吡啶酮;  紫外线吸收剂;  苯并三唑;  还原
分类号:
TQ610.491
文献标志码:
A
摘要:
    以二氧化硫脲为还原剂，将C.I.分散黄119还原为吡啶酮型苯并三唑紫外线吸收剂UV1，采用紫外可见光谱、红外光谱、核磁氢谱、质谱等分析手段验证了还原产物的分子结构。研究结果表明，紫外线吸收剂UV1在乙醇溶液中的最大吸收波长为329 nm，摩尔消光系数较高。紫外线吸收剂UV1在涤纶织物上有一定的上染能力，适合作为涤纶用紫外线吸收剂。

参考文献/References:

 ［1］ 王建宁. 纺织品抗紫外整理剂的开发与应用研究［D］. 上海： 东华大学， 2005: 13.
［2］ 安秋凤, 王雁, 路德待， 等. 织物用抗紫外线整理剂的研究进展［J］. 化工进展, 2007, 26(6): 819824.
［3］ 李宇, 李宗石. 苯并三唑类紫外线吸收剂的现状及发展趋势［J］. 精细与专用化学品, 2007, 15(5): 57.
［4］ 丁著明, 刘丽湘, 周淑静， 等. 紫外线吸收剂的研究进展［J］. 精细与专用化学品, 2005, 13(13): 510.
［5］ 于淑娟, 郑玉斌, 杜杰， 等. 防晒剂的发展综述［J］. 日用化学工业, 2005, 35(4): 248251.
［6］ Paterson M J, Robb M A, Blancafort L, et al. Theoretical study of benzotriazole UV photostability: ultrafast deactivation through coupled proton and electron transfer triggered by a chargetransfer state［J］. J Am Chem Soc, 2004, 126: 29122922.
［7］ John C. Crawford. 2(2Hydroxyphenyl)2Hbenzotriazole ultraviolet stabilizers［J］. Progress in Polymer Science, 1999, 24: 734.
［8］ Hunger K. Industrial Dyes: Chemistry, Properties, Applications［M］. Weinheim: WILEYVCH Verlag GmbH & Co. KgaA, 2003: 1435.

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备注/Memo

备注/Memo:
 收稿日期： 2010-10-29
基金项目： 浙江省自然科学基金（Y4090227） 
作者简介： 曹益宁（1985-），男，浙江海宁人，硕士研究生，主要从事纺织品染整理论与新技术的研究。
通讯作者： 崔志华，电子邮箱：zhhcui@zstu.edu.cn
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