|本期目录/Table of Contents|

[1]蓝晓倩,殷亚然,雷小英,等.微反应器内棕榈酸甲酯磺酸盐的合成及优化[J].浙江理工大学学报,2026,55-56(自科二):163-174.
 LAN Xiaoqian,YIN Yaran,LEI Xiaoying,et al.Synthesis and optimization of palm methyl ester sulfonate in microreactor[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科二):163-174.
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微反应器内棕榈酸甲酯磺酸盐的合成及优化()

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
55-56
期数:
2026年自科第二期
页码:
163-174
栏目:
出版日期:
2026-03-15

文章信息/Info

Title:
Synthesis and optimization of palm methyl ester sulfonate in microreactor
文章编号:
1673-3851(2026) 03-0163-12
作者:
蓝晓倩 殷亚然雷小英 焦玉峰 张先明
1. 浙江理工大学材料科学与工程学院 ,杭州 310018;2. 现代纺织技术创新中心(鉴湖实验室)
Author(s):
LAN XiaoqianYIN Yaran LEI Xiaoying JIAO Yufeng ZHANG Xianming
1. School of Materials Science& Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Innovation Center of Advanced Textile Technology(Jianhu Laboratory) , Shaoxing 312030, China; 3. Zanyu Technology GroupCo. , Ltd. , Hangzhou 311305, China
关键词:
微反应器表面活性剂 生物柴油磺化反应传质
分类号:
TQ649.5
文献标志码:
A
摘要:
传统间歇式反应器在以氯磺酸为磺化剂合成生物柴油基棕榈酸甲酯磺 酸 盐(MethylPalmitate Sulfonate,MES-C16)表面活性剂时 ,热质传递效率低下 ,导致制备效率低且产品品质差 , 阻碍其工业化应用 。为 了获 得高质量磺酸盐 ,开发了一种混合-磺化微反应器系统 ,通过对氯磺酸与棕榈酸甲酯(MethylPalmitate,MP) 磺化机 理分析、溶剂筛选及工艺优化 ,在微反应器中实现低温磺化;采用红外光谱和核磁氢谱表征产品结构 ,通过直接两相 滴定法和电位滴定法测定产物活性物和二钠盐含量 。结果表明:该研究在 50℃低温条件下成功实现了 MP高效磺 化 ,最终产物活性物含量提升至 76.0% ,二钠盐含量降至 9.8% ,显著优于间歇式反应器;纯化后产品达工业优级品 标准并展现出优异的溶解性、乳化性和泡沫性 。基于微反应器的高效热质传递效率特性 ,该研究为生物柴油基磺酸 盐的高效制备提供新策略。

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备注/Memo

备注/Memo:
基金项目 : 浙 江 省 自 然 科 学 基 金 白 马 湖 实 验 室 联 合 基 金 项 目 (LBMHY25E060002) ; 浙 江 省 “尖 兵 ”“领 雁 ”研 发 攻 关 计 划 项 目 (2023C01095) ;浙江理工大学科研业务费专项项目(24212108-Y)收稿日期 : 2025-03-18 网络出版日期 : 2025-06-03
作者简介 : 蓝晓倩(1999— ) ,女 ,杭州人 ,硕士研究生 ,主要从事阴离子表面活性剂方面的研究。通信作者 : 殷亚然 ,E-mail:yryin@zstu. edu. cn
更新日期/Last Update: 2026-03-06