|本期目录/Table of Contents|

[1]杨扬,FARUK Omar,吕姣姣,等.基于酚胺涂层的超高分子量聚乙烯纤维表面协同功能化改性研究[J].浙江理工大学学报,2026,55-56(自科二):153-162.
　YANG Yang,FARUK Omar,LÜ Jiaojiao,et al.Research on the surface synergistic functional modification of UHMWPE fibers based on phenol-amine coatings[J].Journal of Zhejiang Sci-Tech University,2026,55-56(自科二):153-162.
点击复制

基于酚胺涂层的超高分子量聚乙烯纤维表面协同功能化改性研究()

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
55-56
期数:
2026年自科第二期
页码:
153-162
栏目:
出版日期:
2026-03-15

文章信息/Info

Title:
Research on the surface synergistic functional modification of UHMWPE fibers based on phenol-amine coatings
文章编号:
1673-3851(2026) 03-0153-10
作者:
杨扬; FARUK Omar ; 吕姣姣; 董馨婷; 吴金丹
1. 浙江理工大学绿色低碳染整技术浙江省工程研究中心 ,杭州 310018;2. 浙江省现代纺织技术创新中心 ,浙江绍兴 312030
Author(s):
YANG Yang ; FARUK Omar ; LÜ Jiaojiao ; DONG Xinting ; WU Jindan
1. Zhejiang Provincial Engineering Research Center for Green and Low-Carbon Dyeing& Finishing, Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Zhejiang Provincial Innovation Center of Advanced Textile Technology, Shaoxing312030, China
关键词:
超高分子量聚乙烯; 酚胺涂层; 邻苯二酚; 抗菌性能; 界面剪切强度
分类号:
TQ342.61;TB332
文献标志码:
A
摘要:
为解决超高分子量聚乙烯(Ultra-high molecularweightpolyethylene, UHMWPE) 纤维因低表面能和 惰性而导致的界面黏附性差等问题 , 采用邻苯二酚(Catechol, CAT) 和 1, 6-己二胺(1, 6-Hexanediamine, HDA) 在 UHMWPE 纤维表面构建酚胺涂层 ,并借助金属配位作用在涂层表面沉积 Cu2+ 、Zn2+ 和 Ag+ 。采用傅里叶变换红 外光谱、X射线光电子能谱、扫描电子显微镜及接触角测试等手段 ,表征改性 UHMWPE纤维的表面形貌和化学组 成;通过单丝拔出实验评估其与环氧树脂的界面剪切强度(Interfacialshearstrength, IFSS) ,并通过抗菌测试考察其 对大肠埃希菌和金黄色葡萄球菌的抗菌性能 。结果表明:酚胺改性可以在UHMWPE纤维表面形成稳定涂层 ,从而 有效调控纤维表面粗糙度并显著增强润湿性 ,使纤维/树脂界面黏附性大幅提升 。 当 CAT与 HDA的质量浓度比为 1∶2时 ,改性效果最佳 ,上接触角从 0°升至 23.1°,IFSS提高 136%;此外 ,酚胺涂层为 Cu2+ 、Zn2+ 和 Ag+ 提供了稳定 的锚定位点 ,赋予纤维优异的抗菌性能 ,其中 Ag+ 改性纤维的抗菌率超过 90% 。该研究可为功能性 UHMWPE纤 维复合材料的开发提供一定的理论依据和技术指导。

参考文献/References:

[1]Patel K,Chikkali SH,Sivaram S.Ultrahigh molecular weight polyethylene:Catalysis,structure,properties,processing and applications[J].Progress in Polymer Science,2020,109: 101290.

[2]黄伟，丁金友，陈功林，等.超高分子量聚乙烯纤维制备技术研 究进展[J]. 塑料科技，2025,53(3):161-167.

[3]HeJ,Wang Y,Qian Y,et al.Surface modification of ultra- high-molecular-weight polyethylene and applications:A review [J].Polymers,2024,16(23):3 431.

[4]Chhetri S,Bougherara H.A comprehensive review on surface modification of UHMWPE fiber and interfacial properties[J]. Composites Part A:Applied Science and Manufacturing,2021, 140:106146.

[5]方春月，刘紫璇，贾立霞，等.双等离子体改性超高分子量聚乙 烯复合材料的弹道响应[J].纺织学报，2024,45(2):77-84.

[6]Li C Y,Shi Y M,Zhang R,et al. Effect of surface modifications on the properties of UHMWPE fibres and their composites[J].E-Polymers,2019,19(1):40-49.

[7] ZhangY, Jing Z Y, Jiang G D, et al. A novel PDA/POSS transition layer on the surface of UHMWPE fibers by co- depositing to improve the mechanical properties of composites [J]. Polymer, 2025, 316: 127856.

[8] AlsufyaniSJ, ZakiM F, SolimanTS, etal. Gammaradiation induced tailoring thestructural, optical, surfaceand mechanical propertiesofUHMWPE [J]. ProgressinNuclearEnergy, 2024, 177: 105481.

[9] 李翠玉 , 苏瑞 , 李晓雨 , 等. 复合涂层对 UHMWPE纤维复合材 料界面性能的影响[J]. 化工新型材料 , 2021, 49(11) : 99-103.

[10] Faruk O, YangY, ZhangJ L, etal. A comprehensive review of ultrahigh molecular weight polyethylene fibers for applicationsbasedon theirdifferentpreparation techniques[J]. Advancesin PolymerTechnology, 2023, 2023(1) : 6656692.

[11] 张虹 , 王贵 , 李晓明 , 等. 超高分子量聚乙烯纤维表面改性及 其与水性聚氨酯复合粘接性能的研究[J]. 中国胶粘剂 , 2025, 34(1) : 27-32.

[12] AlfieriM L, WeilT, Ng D Y W , et al. Polydopamine at biological interfaces[J]. Advances in Colloid and Interface Science, 2022, 305: 102689.

[13] Lee H, Dellatore S M, Miller W M, et al. Mussel-inspired surface chemistry for multifunctional coatings[J]. Science, 2007, 318(5849) : 426-430.

[14] Liu Y, FangY C, LiuXL, etal. Mussel-inspiredmodification of carbon fiber via polyethyleneimine/polydopamine co- deposition for the improved interfacial adhesion [ J ]. CompositesScienceand Technology, 2017, 151: 164-173.

[15] 赵晗 , 尚晴 , 杨萌 , 等. 邻苯二酚-四乙烯五胺改性超高分子量 聚乙烯纤维[J]. 高分子学报 , 2020, 51(3) : 287-294.

[16] TarvirdipourS, Abdollahi S N, Köser J, et al. Enhanced antimicrobial protection through surface immobilization of antibiotic-loaded peptide multicompartment micelles [ J ]. JournalofMaterialsChemistryB , 2025, 13(18) : 5365-5379.

[17] BaiS, LiX H, Zhao Y H, et al. Antifogging/antibacterial coatings constructed by N-hydroxyethylacrylamide and quaternary ammonium-containing copolymers [ J ]. ACS Applied Materials & Interfaces, 2020, 12(10) : 12305-12316.

[18] Marzullo P, Gruttadauria M, D’ Anna F. Quaternary ammonium salts-based materials: A review on environmental toxicity, anti-fouling mechanisms and applications in marine and water treatment industries[J]. Biomolecules , 2024, 14(8) : 957.

[19] Liu H F, Zou Q S, Qiao Z, et al. Facile homobifunctional imidoestermodificationofadvancednanomaterialsforenhanced antibiotic synergistic effect[J]. ACS Applied Materials & Interfaces, 2021, 13(34) : 40401-40414.

[20] Zhang L H, Yang J L, Song Y Y, et al. Synergistic antibacterial surface with liquid repellency and enhanced photothermal bactericidal activity[J]. Langmuir, 2023, 39 (24) : 8379-8389.

[21] Liu W J, HeSQ, Liu H, etal. A green, versatile, andfacile strategyforanti -biofoulingsurfacewithultra-highgraftdensity polyethylene glycol[J]. Journalof Nanobiotechnology, 2024, 22(1) : 746.

[22] LvJJ, ZhangC, YangY, etal. One-potsynthesisofcatechol- based antibacterial coating for ultra-high molecular weight polyethylene sutures [ J ]. Colloid and Interface Science Communications, 2025, 67: 100844.

[23] EjimaH, Richardson JJ, Liang K, etal. One-step assembly of coordination complexes for versatile film and particle engineering[J]. Science, 2013, 341(6142) : 154-157.

[24] Ding R, Yuan Z, Wang K, et al. Dual-functional polyetheretherketone surface modification for enhanced osseointegration and antibacterial activity in pH-responsive manner [J]. JournalofMaterialsScience& Technology, 2024, 200: 129-140.

[25] 冯霞 , 胡俊成 , 阿拉东. 多巴胺仿生修饰及聚乙烯亚胺二次功 能化表面改性超高分子量聚乙烯纤维[J]. 天津工业大学学报 , 2016, 35(6) : 14-19.

[26] 俞凌晓 , 吕汪洋 , 王刚强 , 等. 超高分子量聚乙烯织物的表面 接枝改性及其抑菌性能研究[J]. 现代纺织技术 , 2022, 30(2) : 134-140.

[27] Jiang S Y, Niu H, Wang S T, et al. Novel and high- performance tannin-polyamine adhesive: New insight into phenol-amine chemistry[J]. Industrial Crops and Products, 2023, 192: 116129.

[28] Liu Z Q, Yu W , ShengW B, etal. Controllable synthesis of polyphenolspheres via amine-catalyzed polymerization-induced self-assembly[J]. Biomacromolecules, 2022, 23(1) : 140-149.

[29] 汪维海 , 陈宏 , 黄志超 , 等. 多酚-氨基硅烷改性超高分子量聚 乙烯纤维的制备及其界面性能[J]. 现代纺织技术 , 2022, 30 (6) : 63-72.

相似文献/References:

[1]汪凯,张顺花,林启松.超高分子量聚乙烯/聚丙烯复合材料的非等温结晶动力学研究[J].浙江理工大学学报,2018,39-40(自科4):429.
　WANG Kai,ZHANG Shunhua,LIN Qisong.Study of nonisothermal crystallization kinetics of ultrahigh molecular weight polyethylene /polypropylene composites[J].Journal of Zhejiang Sci-Tech University,2018,39-40(自科二):429.
[2]卢鑫,齐晓明,张鹏,等.高密度聚乙烯/超高分子量聚乙烯共混物的制备及其性能研究[J].浙江理工大学学报,2025,53-54(自科五):589.
　LU Xin,QI Xiaoming,ZHANG Peng,et al.A study on the preparation and properties of high density polyethylene/ultra high molecular weight polyethylene blends[J].Journal of Zhejiang Sci-Tech University,2025,53-54(自科二):589.

备注/Memo

备注/Memo:
基金项目 : 浙江省重点研发计划项目(2023C01093)收稿日期 : 2025-06-07 网络出版日期 : 2025-09-17
作者简介 : 杨 扬(1995— ) ,男 ,安徽黄山人 ,博士研究生 ,主要从事复合纤维改性方面的研究。通信作者 : 吴金丹 ,E-mail:wujindan@zstu. edu. cn
更新日期/Last Update: 2026-03-06