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[1]李佳洺,汪大中,张凌豪,等.多功能碳包覆Na2MnPO4F材料的制备及其储钠性能研究[J].浙江理工大学学报,2025,53-54(自科六):774-785.
　LI Jiaming,WANG Dazhong,ZHANG Linghao,et al.A study on the preparation of a multifunctional carbon-coated Na2MnPO4F material and its sodium storage properties[J].Journal of Zhejiang Sci-Tech University,2025,53-54(自科六):774-785.
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多功能碳包覆Na2MnPO4F材料的制备及其储钠性能研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第53-54卷
期数:
2025年自科第六期
页码:
774-785
栏目:
出版日期:
2025-11-10

文章信息/Info

Title:
A study on the preparation of a multifunctional carbon-coated Na2MnPO4F material and its sodium storage properties
文章编号:
1673-3851(2025)11-0774-12
作者:
李佳洺; 汪大中; 张凌豪; 夏琦博; 孙俊杰; 杨叶锋
浙江理工大学材料科学与工程学院,杭州310018
Author(s):
LI Jiaming;  WANG Dazhong;  ZHANG Linghao;  XIA Qibo;  SUN Junjie;  YANG Yefeng
School of Materials Science & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
钠离子电池; 正极材料; 锰基聚阴离子型; 球磨法; 碳包覆
分类号:
TQ325.12
文献标志码:
A
摘要:
为解决 Na2MnPO4F(NMPF)聚阴离子型化合物电子电导率差和离子扩散速率低的问题,开发高性能钠离子电池正极材料,采用两步球磨法制备了碳包覆的 NMPF正极材料,通过优化碳源添加量和分配方式对碳与NMPF进行均匀复合与包覆,并分析不同碳源添加量和分配方式对 NMPF正极材料电化学性能的影响。结果表明:通过两步球磨法分步等量添加碳源,碳源与锰源比例为4∶1时制备得到的碳包覆复合正极材料(NMPF-4/1),在0.05C下初始放电容量达121mAh/g,150次循环后容量保持率达50%,0.10C下倍率性能测试可逆容量为100mAh/g。该研究为开发高性能钠离子电池正极材料提供了新思路,有望推动钠离子电池在储能领域的广泛应用。

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备注/Memo

备注/Memo:
收稿日期 :2025-04-21 网络出版日期 :2025-06-03 基金项目 : 浙江省自然科学基金项目 (LY21E020010) 作者简介 : 李佳洺 (2000— ), 女 , 辽宁抚顺人 , 硕士研究生 , 主要从事钠离子电池正极材料方面的研究 。 通信作者 : 杨叶锋 ,E-mail:yangyf@zstu.edu.cn
更新日期/Last Update: 2025-11-21