|本期目录/Table of Contents|

[1]江琦,林萍,吴小平,等.NiCoO2/Ag3PO4异质结的制备及其光催化性能分析[J].浙江理工大学学报,2025,53-54(自科一):1-9.
 JIANG Qi,LIN Ping,WU Xiaoping,et al.Preparation of NiCoO2/Ag3PO4 heterojunction and analysis of its photocatalytic properties[J].Journal of Zhejiang Sci-Tech University,2025,53-54(自科一):1-9.
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NiCoO2/Ag3PO4异质结的制备及其光催化性能分析()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第53-54卷
期数:
2025年自科第一期
页码:
1-9
栏目:
出版日期:
2025-01-10

文章信息/Info

Title:
Preparation of NiCoO2/Ag3PO4 heterojunction and analysis of its photocatalytic properties
文章编号:
1673-3851 (2025) 01-0001-09
作者:
江琦林萍吴小平崔灿
浙江理工大学理学院,杭州 310018
Author(s):
JIANG Qi LIN Ping WU Xiaoping CUI Can
School of Science, Zhejiang SciTech University, Hangzhou 310018, China
关键词:
磷酸银镍钴氧化物光催化Z型异质结降解
分类号:
TB33
文献标志码:
A
摘要:
磷酸银(Ag 3PO 4)普遍存在高载流子复合率、严重的光腐蚀和相对较大的颗粒尺寸等问题,极大地限制了其光催化性能;为增强Ag 3PO 4的光催化性能,通过构建异质结来促进载流子分离。采用原位沉积法制备Ag 3PO 4与镍钴氧(NiCoO 2)复合材料NiCoO 2/Ag3PO 4,通过X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、荧光光谱(PL)、紫外可见漫反射光谱(UVvis DRS)等手段对该材料的组成、微观结构和光学性质等进行表征与分析。以甲基橙(MO)为模拟污染物,研究了NiCoO 2/Ag 3PO 4复合材料的光催化性能。结果表明:在复合材料NiCoO 2/Ag 3PO 4中,Ag 3PO 4纳米颗粒直径约为16 nm,均匀附着在纳米花状NiCoO 2表面,两者形成Z型异质结;异质结的吸收边发生红移,光电性能得到明显增强;异质结的光催化性能显著提升,在全光谱照射下降解MO的速率是NiCoO 2的15 15倍,Ag 3PO 4的1 84倍,并且在重复使用3次后光催化性能也无明显下降。本文所制备的NiCoO 2/Ag 3PO 4复合材料具有较强的光催化活性和稳定性,有望广泛应用于印染废水处理。

参考文献/References:

[1]Qiu H X, Yamamoto A, Yoshida H. Gallium oxide assisting Ag-loaded calcium titanate photocatalyst for carbon dioxide reduction with water[J]. ACS Catalysis, 2023, 13(6): 3618-3626.
[2]Qi Y, Zhang J W, Kong Y, et al. Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting[J]. Nature Communications, 2022, 13: 484.
[3]Shi X W, Dai C, Wang X, et al. Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution[J]. Nature Communications, 2022, 13: 1287.
[4]Wu Y, Wang H, Tu W G, et al. Construction of hierarchical 2D-2D Zn3In2S6/fluorinated polymeric carbon nitride nanosheets photocatalyst for boosting photocatalytic degradation and hydrogen production performance[J]. Applied Catalysis B: Environmental, 2018, 233: 58-69.
[5]Zhu P F, Hu M, Duan M, et al. High visible light response Z-scheme Ag3PO4/g-C3N4/ZnO composite photocatalyst for efficient degradation of tetracycline hydrochloride: Preparation, properties and mechanism[J]. Journal of Alloys and Compounds, 2020, 840: 155714.
[6]Miao X L, Yue X Y, Ji Z Y, et al. Nitrogen-doped carbon dots decorated on g-C3N4/Ag3PO4 photocatalyst with improved visible light photocatalytic activity and mechanism insight[J]. Applied Catalysis B: Environmental, 2018, 227: 459-469.
[7]Chen G D, Sun M, Wei Q, et al. Ag3PO4/graphene-oxide composite with remarkably enhanced visible-light-driven photocatalytic activity toward dyes in water[J]. Journal of Hazardous Materials, 2013, 244/245: 86-93.
[8]Li Y, Wang P F, Huang C P, et al. Synthesis and photocatalytic activity of ultrafine Ag3PO4 nanoparticles on oxygen vacated TiO2[J]. Applied Catalysis B: Environmental, 2017, 205: 489-497.
[9]Cui C, Li S, Qiu Y W, et al. Fast assembly of Ag3PO4 nanoparticles within three-dimensional graphene aerogels for efficient photocatalytic oxygen evolution from water splitting under visible light[J]. Applied Catalysis B: Environmental, 2017, 200: 666-672.
[10]Shao B B, Liu X J, Liu Z F, et al. A novel double Z-scheme photocatalyst Ag3PO4/Bi2S3/Bi2O3 with enhanced visible-light photocatalytic performance for antibiotic degradation[J]. Chemical Engineering Journal, 2019, 368: 730-745.

备注/Memo

备注/Memo:
收稿日期: 2024-01-22
网络出版日期:2024-06-12
基金项目: 浙江省自然科学基金项目(LHZSD24E020001)
作者简介: 江琦(1999—),男,浙江衢州人,硕士研究生,主要从事光催化材料的研究
通信作者: 崔灿,E-mail:cuican@zstu.edu.cn
更新日期/Last Update: 2025-01-07