|本期目录/Table of Contents|

[1]朱祥祥,孙辉,于斌.聚苯胺/MXene@聚丙烯复合非织造柔性pH值传感器的制备及其传感性能[J].浙江理工大学学报,2024,51-52(自科四):419-426.
　ZHU Xiangxiang,SUN Hui,YU Bin.Preparation and sensing performance of a PANI/MXene@PP  complex nonwoven flexible pH sensor[J].Journal of Zhejiang Sci-Tech University,2024,51-52(自科四):419-426.
点击复制

聚苯胺/MXene@聚丙烯复合非织造柔性pH值传感器的制备及其传感性能()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第51-52卷
期数:
2024年自科第四期
页码:
419-426
栏目:
出版日期:
2024-07-10

文章信息/Info

Title:
Preparation and sensing performance of a PANI/MXene@PP  complex nonwoven flexible pH sensor
文章编号:
1673-3851 (2024)04-0419-08
作者:
朱祥祥; 孙辉; 于斌
1.浙江理工大学纺织科学与工程学院（国际丝绸学院），杭州 310018；2.浙江省现代纺织技术创新中心，浙江绍兴 312000
Author(s):
ZHU Xiangxiang;  SUN Hui;  YU Bin
1.College of Textile Science and Engineering( International Institute of Silk),Zhejiang Sci-Tech University,Hangzhou310018,China;2.Zhejiang Provincial Center of Advanced Textile Technology,Shaoxing312000,China
分类号:
TP212;TS176
文献标志码:
A
摘要:
为制备基于聚丙烯纺黏非织造材料(Polypropylene spunbonded nonwoven fabric，PP SF)的双电极柔性pH值传感器，在PP SF表面涂覆油性聚氨酯（Oil-based polyurethane，OPU），制备得到OPU/PP SF，采用丝网印刷技术将作为参比电极的银/氯化银（Ag/AgCl）浆料和导电碳浆料分别移印至OPU/PP SF表面；利用化学氧化聚合法制备了酸掺杂聚苯胺（Polyaniline，PANI），将其与经超疏水改性的F-Ti3C2Tx MXene结合，再涂覆在C层表面，形成PANI/F-Ti3C2Tx MXene@PP SF柔性pH值传感器。结果表明：PANI/F-Ti3C2Tx MXene@PP SF柔性pH值传感器表面呈现珊瑚状结构，在pH值为2~10时，PANI/F-Ti3C2Tx MXene@PP SF柔性pH值传感器表现出良好的力学性能，其拉伸强度和断裂伸长率均比PP SF有所提高，灵敏度（-37.07 mV/pH）高，线性度（ R2=0.98）好，具有低电位变化率（0.092 mV/h）和良好的重现性（灵敏度标准偏差为0.36%）。该研究可为基于聚丙烯纺黏非织造材料基材的柔性pH值传感器的研究提供参考。

参考文献/References:

［1］ManjakkalL, Dervin S, Dahiya R. Flexible potentiometric pH sensors for wearable systems［J］. RSC Advances, 2020, 10(15): 8594-8617.
［2］LiY Q, Mao Y L, Xiao C, et al. Flexible pH sensor based on a conductive PANI membrane for pH monitoring［J］. RSC Advances, 2019, 10(1): 21-28.
［3］OhS Y, Hong S Y, Jeong Y R, et al. Skin-attachable, stretchable electrochemical sweat sensor for glucose and pH detection［J］. ACS Applied Materials & Interfaces, 2018, 10(16): 13729-13740.
［4］SinghK, Lou B S, Her J L, et al. Super Nernstian pH response and enzyme-free detection of glucose using sol-gel derived RuO xon PET flexible-based extended-gate field-effect transistor［J］. Sensors and Actuators B: Chemical, 2019, 298: 126837.
［5］LiaoY H, Lai H. Investigation of a wireless real-time pH monitoring system based on ruthenium dioxide membrane pH sensor［J］. IEEE Transactions on Instrumentation and Measurement, 2020, 69(2): 479-487.
［6］NyeinH Y Y, Gao W, Shahpar Z, et al. A wearable electrochemical platform for noninvasive simultaneous monitoring of Ca2+and pH［J］. ACS Nano, 2016, 10(7): 7216-7224.
［7］SinghK, Pang S T, Pan T M. Amorphous ZnSn x O yfabricated at room-temperature for flexible pH-EGFET sensor［J］. IEEE Transactions on Electron Devices, 2021, 68(2): 793-797.
［8］RahimiR, Ochoa M, Tamayol A, et al. Highly stretchable potentiometric pH sensor fabricated via laser carbonization and machining of Carbon-Polyaniline composite［J］. ACS Applied Materials & Interfaces, 2017, 9(10): 9015-9023.
［9］PiroL, Lamanna L, Guido F, et al. Flexible SAW microfluidic devices as wearable pH sensors based on ZnO nanoparticles［J］. Nanomaterials, 2021, 11(6): 1479.
［10］PanT M, Huang Y H, Her J L, et al. Solution processed ZnIn x O ysensing membranes on flexible PEN for extended-gate field-effect transistor pH sensors［J］. Journal of Alloys and Compounds, 2020, 822: 153630.

备注/Memo

备注/Memo:
收稿日期： 2023-12-11
网络出版日期：2024-03-13
基金项目： 浙江省自然科学基金项目(LTGS23E030005)；浙江省“高层次特殊人才支持计划”科技创新领军人才项目(2021R52031)
作者简介： 朱祥祥(1999—)，男，安徽阜阳人，硕士研究生，主要从事柔性pH传感器制备方面的研究
通信作者： 孙辉，E-mail：wlzxjywl@126.com
更新日期/Last Update: 2024-08-01