|本期目录/Table of Contents|

[1]段银河,蒋付良,董慧娴,等.交联型氟硅改性聚丙烯酸酯乳胶及其在涤纶织物染色中的应用研究[J].浙江理工大学学报,2024,51-52(自科三):329-336.
 DUAN Yinhe,JIANG Fuliang,DONG Huixian,et al.Preparation of cross linked fluorosilicone modified polyacrylate latex and its application in dyeing of polyester fabrics[J].Journal of Zhejiang Sci-Tech University,2024,51-52(自科三):329-336.
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交联型氟硅改性聚丙烯酸酯乳胶及其在涤纶织物染色中的应用研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第51-52卷
期数:
2024年自科第三期
页码:
329-336
栏目:
出版日期:
2024-05-10

文章信息/Info

Title:
Preparation of cross linked fluorosilicone modified polyacrylate latex and its application in dyeing of polyester fabrics
文章编号:
1673-3851 (2024) 05-0329-08
作者:
段银河蒋付良董慧娴王静吴明华王莉莉余德游王懿佳
1.浙江理工大学a.纺织科学与工程学院(国际丝绸学院);b.生态染整技术教育工程中心,杭州 310018;2.嘉兴市食品药品与产品质量检验检测院,浙江嘉兴 314050
Author(s):
DUAN Yinhe JIANG Fuliang DONG Huixian WANG Jing WU Minghua WANG Lili  YU Deyou WANG Yijia
1a.College of Textile Science and Engineering (International Institute of Silk); 1b.Engineering Research Center for Eco Dyeing & Finishing of Textiles, Ministry of Education of China, Zhejiang  Sci-Tech University, Hangzhou 310018, China; 2.Jiaxing Food and Drug and Product Quality Inspection and Testing Center, Jiaxing 314050, China
关键词:
交联氟硅改性聚丙烯酸酯涤纶免水洗染色分散染料
分类号:
TS195-644
文献标志码:
A
摘要:
为提高涤纶织物分散染料免水洗热熔染色织物的染色性能,以甲基丙烯酸甲酯(MMA)和丙烯酸异辛酯(2-EHA)为聚合单体,以甲基丙烯酸三氟乙酯(3FMA)和侧链乙烯基聚硅氧烷(PDViS)为改性剂,以烯丙基聚氧乙烯醚(F-6)和烯烃氧基磺酸盐(DNS-86)为乳化剂,通过细乳液聚合法,制备了交联型氟硅改性聚丙烯酸酯(PDViS-HPFA)乳胶,通过XPS、EDS和WAC等手段表征PDViS-HPFA胶膜的表面化学组成和性能,并将乳胶应用于涤纶织物分散染料免水洗热熔染色中;探究PDViS-HPFA乳胶质量分数、焙烘温度和焙烘时间对染色织物 K/S 值和耐摩擦色牢度的影响,并优化了染色工艺条件。结果表明:PDViS-HPFA胶膜表面富集了氟硅元素,且沿胶膜由内向外逐渐增加,PDViS-HPFA胶膜的接触角为103.2°,吸水率为5.21%,具有较强的疏水性;在PDViS-HPFA乳胶质量分数为7%、焙烘温度为200 ℃、焙烘时间为3 min的轧染工艺条件下,染色织物的 K/S 值高达16.442,耐干湿摩擦色牢度分别为4~5级和4级,防泳移达5级,高于同类改性聚丙烯酸酯乳胶。该文采用3FMA和PDViS协同改性聚丙烯酸酯乳胶,有效提升了染色织物得色量、色牢度和染色均匀性,为提高涤纶分散染料免水洗热熔染色性能提供参考。

参考文献/References:

1 AiL, Cao H M, Zhu Y W. Ultralow emission micro - printing process for PET fibers using liquid disperse dye J . Textile Research Journal, 2021, 92(5 - 6):788 - 800.

2LeeW J, Kim J P. Aftertreatment of polyester fabric dyed with temporarily solubilised disperse dyesJ.Coloration Technology, 2010, 116(11):345-348.

3LiL, Chu R, Yang Q, et al. Performance of washing-free printing of disperse dye inks: Influence of water-borne polymersJ. Polymers, 2022, 14(20): 4277.

4WangL, Cui S, Ni H, et al. Preparation and application of polyacrylate binder for washing-free printing on polyester with disperse dyesJ.Textile Research Journal, 2018, 89(13):2721-2728.

5TianY, Huang X, Cheng Y, et al. Applications of adhesives in textiles: A reviewJ. European Polymer Journal, 2022,167:111089.

6HansenC M. Polymer additives and solubility parametersJ. Progress in Organic Coatings, 2004, 51(2):109-112.

7AtaeefardM, Mohseni M, Moradian S. Polypropylene/clay nanocomposite: Kinetic and thermodynamic of dyeing with various disperse dyes J. The Journal of The Textile Institute, 2015, 107(2):182-190.

8VenkatramS, Kim C, Chandrasekaran A, et al. Critical assessment of the Hildebrand and Hansen Solubility Parameters for polymers J. Journal of Chemical Information and Modeling, 2019, 59(10):4188-4194.

9WangL L, Cui S S, Ni H G, et al. New washing-free printing binder based on organosilicon-modified polyacrylate for polyester fabric printing of disperse dyes J. Progress in Organic Coatings, 2018, 123:75-81.

10FangC, Xue J. Preparation and characterization of polyacrylate emulsion pressure-sensitive adhesives with various lengths of fluorinated side chainsJ.Journal of Adhesion Science and Technology, 2021,36(10):1041-1059.

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备注/Memo

备注/Memo:
收稿日期: 2023-11-15
网络出版日期:2024-02-09
基金项目: 国家自然科学基金项目(62173307) ;浙江省重点研发计划项目(2021C01058)
作者简介: 段银河(1998-),女,云南大理人,硕士研究生,主要从事生态染整技术研发方向的研究
通信作者: 吴明华,E-mail:wmh@zstu.edu.cn
更新日期/Last Update: 2024-06-19