|本期目录/Table of Contents|

[1]陈龙,吴小平,崔灿.α-FeOOH与Ag3PO4异质结复合材料的制备及光催化性能[J].浙江理工大学学报,2023,49-50(自科六):691-700.
 CHEN Long,WU Xiaoping,CUI Can.Fabrication of an α-FeOOH and Ag3PO4 heterojunction composite and its photocatalytic performance[J].Journal of Zhejiang Sci-Tech University,2023,49-50(自科六):691-700.
点击复制

α-FeOOH与Ag3PO4异质结复合材料的制备及光催化性能()
分享到:

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第49-50卷
期数:
2023年自科第六期
页码:
691-700
栏目:
出版日期:
2023-11-10

文章信息/Info

Title:
Fabrication of an α-FeOOH and Ag3PO4 heterojunction composite and its photocatalytic performance
文章编号:
1673-3851 (2023) 11-0691-10
作者:
陈龙吴小平崔灿
浙江理工大学材料科学与工程学院,杭州 310018
Author(s):
CHEN Long WU Xiaoping CUI Can
School of Materials Science & Engineering, Zhejiang SciTech University, Hangzhou 310018, China
关键词:
Ag3PO4α-FeOOH光催化异质结降解
分类号:
TB33
文献标志码:
A
摘要:
针对磷酸银(Ag3PO4)和羟基氧化铁(α-FeOOH)等材料因光生载流子复合速率过快而导致光催化性能差的问题,通过制备α-FeOOH与Ag3PO4的异质结复合材料(α-FeOOH@Ag3PO4)来促进光生载流子的分离,从而提升材料的光催化性能。首先采用简单的水热法制备由纳米片组成的具有分级结构的α-FeOOH微球,然后使用原位沉积工艺将Ag3PO4颗粒均匀沉积在α-FeOOH微球表面,制备得到α-FeOOH@Ag3PO4;分析所得异质结复合材料的微观结构、光吸收性能、亚甲基蓝降解性能和光电性能。结果表明:具有分级结构的α-FeOOH微球有利于Ag3PO4颗粒沉积,Ag3PO4颗粒粒径为3~8 nm;α-FeOOH@Ag3PO4吸收边发生红移,光电性能显著增强;α-FeOOH@Ag3PO4的光催化效率是α-FeOOH的75.0倍,是Ag3PO4的1.8倍;α-FeOOH@Ag3PO4是Type-Ⅱ型半导体异质结,光生载流子在异质结界面有效分离,提高了光催化效率和材料的稳定性。α-FeOOH@Ag3PO4具有较强的光催化活性,在光催化治理水污染领域有着广阔的应用前景。

参考文献/References:

1 Giannakis S. A review of the concepts, recent advances and niche applications of the (photo) Fenton process, beyond water/wastewater treatment: Surface functionalization, biomass treatment, combatting cancer and other medical uses J . Applied Catalysis B: Environmental, 2019, 248: 309319.

2 Maeda K, Mallouk T E. Twodimensional metal oxide nanosheets as building blocks for artificial photosynthetic assemblies J . Bulletin of the Chemical Society of Japan, 2019, 92(1): 3854.

3 Roy N, Suzuki N, Terashima C, et al. Recent improvements in the production of solar fuels: From CO2 reduction to water splitting and artificial photosynthesis J . Bulletin of the Chemical Society of Japan, 2019, 92(1): 178192.

4 Teng F, Liu Z L, Zhang A, et al. Photocatalytic performances of Ag3PO4 polypods for degradation of dye pollutant under natural indoor weak light irradiation J . Environmental Science & Technology, 2015, 49(16): 94899494.

5 Cai T, Liu Y T, Wang L L, et al. Silver phosphatebased ZScheme photocatalytic system with superior sunlight photocatalytic activities and antiphotocorrosion performance J . Applied Catalysis B: Environmental, 2017, 208: 113.

6 ]〖 JP2 Grilla E, Petala A, Frontistis Z, et al. Solar photocatalytic JP4 abatement of sulfamethoxazole over Ag3PO4/WO3 composites J . Applied Catalysis B: Environmental, 2018, 231: 7381.

7 ]怀燕瑾 , 岳喜龙 , 吴彤 , . Ag3PO4/gC3N4 复合材料的光催化及抗菌性能[ J . 能源研究与管理 , 2022, 14(4): 110115.

8 Patil S S, Patil D R, Apte S K, et al. Confinement of Ag3PO4 nanoparticles supported by surface plasmon resonance of Ag in glass: Efficient nanoscale photocatalyst for solar H2 production from waste H2S J . Applied Catalysis B: Environmental, 2016, 190: 7584.

9 Mohanty S, Babu P, Parida K, et al. Surfaceplasmonresonanceinduced photocatalysis by coreshell SiO2@AgNCs@Ag3PO4 toward watersplitting and phenol oxidation reactions J . Inorganic Chemistry, 2019, 58(15): 96439654.

10 Zhang Y Y, Wang L L, Park S H, et al. Single nearinfraredlaser driven Zscheme photocatalytic H2 evolution on upconversion material@Ag3PO4@black phosphorus J . Chemical Engineering Journal, 2019, 375: 121967.

备注/Memo

备注/Memo:

收稿日期: 2023-02-13

基金项目: 浙江省自然科学基金项目(LY20F040006)

作者简介: 陈龙(1998- ),男,江苏南通人,硕士研究生,主要从事光催化材料制备与应用方面的研究。

通信作者: 崔灿,Email:cuican@zstu.edu.cn

更新日期/Last Update: 2023-11-14