|本期目录/Table of Contents|

[1]张先盛,赵素芳,吴金丹,等.pH值响应性电荷可翻转聚合物多层膜的构建及其抗菌性能[J].浙江理工大学学报,2020,43-44(自科四):512-519.
 ZHANG Xiansheng,ZHAO Sufang,WU Jindan,et al.Construction of pHresponsive chargereversible polymer multilayers and its antibacterial properties[J].Journal of Zhejiang Sci-Tech University,2020,43-44(自科四):512-519.
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pH值响应性电荷可翻转聚合物多层膜的构建及其抗菌性能()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第43-44卷
期数:
2020年自科四期
页码:
512-519
栏目:
出版日期:
2020-07-10

文章信息/Info

Title:
Construction of pHresponsive chargereversible polymer multilayers and its antibacterial properties
文章编号:
1673-3851 (2020) 07-0512-08
作者:
张先盛赵素芳吴金丹王际平
1. 浙江理工大学,a.生态染整技术教育部工程研究中心;b.先进纺织材料与制备技术教育部重点实验室,杭州 310018;2. 上海工程技术大学服装学院, 上海 201620
Author(s):
ZHANG Xiansheng ZHAO Sufang WU Jindan WANG Jiping
1a. Engineering Research Center for EcoDyeing and Finishing of Textiles, Ministry of Education; 1b. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Zhejiang SciTech University, Hangzhou 310018, China;2. Fashion College, Shanghai University of Engineering Science, Shanghai 201620, China
关键词:
多层膜层层自组装等电点pH响应表面电荷抗菌材料抗菌性能
分类号:
Q5
文献标志码:
A
摘要:
利用体内细菌感染部位微环境偏酸的特点,设计具有pH值响应性的聚电解质多层膜,利用层层自组装技术组装得到多层膜,并用光敏交联剂进行共价交联,改变组装层数、聚丙烯酸(PAA)分子量、聚阳离子组装浓度和种类等组装条件,分析多层膜表面Zeta电位随pH值变化的趋势。结果表明:PAA分子量和聚阳离子种类对多层膜的等电点影响最为显著;优化组装条件后所获得的(PAA/PAH)5、(PAA/QCS)5和(PAA/BPEI)5多层膜均在酸性条件下收缩,在pH值74条件下膨胀;(PAA/PAH)5和(PAA/BPEI)5多层膜均在pH值50时高效杀菌,在pH值74时可有效阻粘,保持表面不被细菌污染。研究获得了多层膜结构与pH响应性能的构效关系规律,为安全、高效和智能的抗菌材料的设计提供新的思路。

参考文献/References:

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[8] Cao Z, Mi L, Mendiola J, et al. Reversibly switching the function of a surface between attacking and defending against bacteria[J]. Angewandte Chemie International Edition, 2012, 51(11): 2602-2605.
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备注/Memo

备注/Memo:
收稿日期:2019-10-15
网络出版日期: 2020-03-05
基金项目:国家自然科学基金项目(21604072)
作者简介:张先盛(1992-),男,安徽铜陵人,硕士研究生,主要从事智能抗菌材料方面的研究
通信作者:吴金丹,E-mail:wujindan@zstu.edu.cn
更新日期/Last Update: 2020-07-06