|本期目录/Table of Contents|

[1]崔正阳,罗丹丹,冯翠,等.碲化镉量子点掺杂的羟基磷灰石荧光探针制备及其在铜离子检测中的应用[J].浙江理工大学学报,2019,41-42(自科一):49-55.
　CUI Zhengyang,LUO Dandan,FENG Cui,et al.Preparation of hydroxyapatite fluorescent probe doped with CdTe quantum dots and its application in copper ion detection[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科一):49-55.
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碲化镉量子点掺杂的羟基磷灰石荧光探针制备及其在铜离子检测中的应用()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第41-42卷
期数:
2019年自科一期
页码:
49-55
栏目:
出版日期:
2018-12-15

文章信息/Info

Title:
Preparation of hydroxyapatite fluorescent probe doped with CdTe quantum dots and its application in copper ion detection
文章编号:
1673-3851 (2019) 01-0049-07
作者:
崔正阳; 罗丹丹; 冯翠; 马矢徒; 孔祥东
浙江理工大学，a.生命科学学院；b.材料与纺织学院，杭州 310018
Author(s):
CUI Zhengyang;  LUO Dandan;  FENG Cui;  MA Shitu;  KONG Xiangdong
a.College of Life Science; b.College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
羟基磷灰石; 量子点; 铜离子检测; 荧光探针
分类号:
Q279
文献标志码:
A
摘要:
在水热法合成羟基磷灰石颗粒（Hydroxyapatite，HAp）的过程中加入碲化镉（CdTe）量子点前体，合成可激发出红色荧光的羟基磷灰石/碲化镉（HAp/CdTe）荧光探针，对所得荧光探针的形貌、大小和荧光特性进行表征，并探究其在铜离子检测领域应用的可行性。结果表明：所得HAp/CdTe荧光探针为针状实心颗粒，长径约为350 nm，短径约为80 nm；HAp/CdTe荧光探荧光强度较高、发射光谱范围较窄和其荧光强度有良好的pH和温度稳定性；在用于铜离子检测方面，铜含量为1.3～51.2 mg/L范围内，探针的荧光强度变化与Cu2+浓度之间呈现出良好的线性关系，相关系数为0.9986，检测限为0.4 mg/L，且其他离子（Na+、Mg2+、Ca2+、Li+、NH4+、K+和Cd2+）对该检测方法无明显干扰作用。合成的HAp/CdTe荧光探针具有制备方法简单、成本较低、荧光性质稳定和可长期保存的特点，是作为检测铜离子浓度的理想材料。

参考文献/References:

［1］ Chen Z, Meng H, Xing G, et al. Acute toxicological effects of copper nanoparticles in vivo［J］. Toxicology Letters, 2006,163(2): 109-120.
［2］ Lu Y, Jiang H, Zhang N Q, et al. Assembly and copper ions detection of highly sensible and stable hydroxyapatite  nanocomposite fluorescence probe［J］. Micro & Nano Letters,2014,9(2):127-131.
［3］ Pinto J J, Moreno C, GarcíaVargas M. A very sensitive  flow system for the direct determination of copper in natural waters based on spectrophotometric detection［J］. Talanta,2004,64(2):562-565.
［4］ Pourreza N, Hoveizavi R. Simultaneous preconcentration of  Cu, Fe and Pb as methylthymol blue complexes on naphthalene adsorbent and flame atomic absorption determination［J］. Analytica Chimica Acta,2005,549(1/2):124-128.
［5］ Becker J S, Zoriy M V, Pickhardt C, et al. Imaging of Copper, Zinc, and other elements in thin section of human brain samples (hippocampus) by laser ablation inductively coupled plasma mass spectrometry［J］. Analytical Chemistry,2005,77(10):3208.
［6］ 向雨秘,龙少波,朱勍.铜离子荧光探针的研究进展［J］.浙江化工,2013,44(2):18-22.
［7］ 孟圆圆,魏凤,祁海平.痕量铜离子的测定进展［J］.广州化工,2015,12(1):15-16.
［8］ 翁文婷.4,6二溴荧光素荧光法测定微量铜离子的研究［J］.泉州师范学院学报,2007,25(2):71-74.
［9］ 宋国龙,赵雪芹,孔祥东.Ca 2+对CdTe量子点复合丝素蛋白凝胶的影响［J］.蚕桑通报,2016,47(1):16-19.

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备注/Memo

备注/Memo:
收稿日期： 2018-03-12
网络出版日期： 2018-10-09
作者简介： 崔正阳（1992-），男，河南永城人，硕士研究生，主要从事生物纳米材料方面的研究
通信作者： 孔祥东，E-mail:kxd01@126.com
更新日期/Last Update: 2019-03-13