|本期目录/Table of Contents|

[1]田小平,易玲敏,孟晓美.聚醚改性氟硅表面活性剂的合成与溶液性质研究[J].浙江理工大学学报,2014,31-32(自科6):636-640.
　TIAN Xiao ping,YI Ling min,MENG Xiao mei.Research on Synthesis and Solution Properties of Polyether Modified Fluorosilicone Surfactant[J].Journal of Zhejiang Sci-Tech University,2014,31-32(自科6):636-640.
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聚醚改性氟硅表面活性剂的合成与溶液性质研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第31-32卷
期数:
2014年自科6期
页码:
636-640
栏目:
(自科)纺织与服装工程
出版日期:
2014-11-10

文章信息/Info

Title:
Research on Synthesis and Solution Properties of Polyether Modified Fluorosilicone Surfactant
文章编号:
1673-3851 (2014) 06-0636-05
作者:
田小平;  易玲敏;  孟晓美
浙江理工大学, a. 先进纺织材料与制备技术教育部重点实验室; b. 生态染整技术教育部工程研究中心, 杭州 310018
Author(s):
TIAN Xiaoping;  YI Lingmin;  MENG Xiaomei
a. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education; b. Engineering Research Center for Eco Dyeing & Finishing of Textiles, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
氟硅;  硅氢加成;  表面活性剂;  溶液性质
分类号:
TS195.644
文献标志码:
A
摘要:
通过阴离子开环聚合和硅氢加成反应得到聚醚改性氟硅表面活性剂和聚醚改性硅氧烷表面活性剂;并用核磁和红外来表征其结构。对聚醚改性有机硅表面活性剂和氟硅氧烷表面活性剂以及全氟表面活性剂进行溶液性质的研究发现:全氟表面活性剂的最小表面张力最低,聚醚改性氟硅表面活性剂的最小表面张力比聚醚改性的硅氧烷要高;对于相同的亲水链段和疏水链段聚醚改性的氟硅氧烷,其临界胶束浓度(CMC)比聚醚改性硅氧烷小;聚醚改性硅氧烷亲水链段的长度增加,CMC减少;而聚醚改性氟硅氧烷的疏水链段长度增加,CMC增加。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期： 2014-01-08
基金项目： 国家自然科学基金(21276243);浙江省重点科技创新团队项目(2012R10038-14)
作者简介： 田小平(1986-),男,湖北黄冈人,硕士研究生,主要从事有机氟硅高分子材料的研究
通信作者： 易玲敏,E-mail,lmyi@zstu.edu.cn
更新日期/Last Update: 2014-11-19