|本期目录/Table of Contents|

[1]李艳,吴俭俭,刘海山,等.碳骨架气相色谱法测定纺织助剂中短链氯化石蜡[J].浙江理工大学学报,2014,31-32(自科6):599-604.
 LI Yan,WU Jian jian,LIU Hai shan,et al.Measurement of Short Chain Chlorinated Paraffins in Textile Assistant with Carbon Skeleton Gas Chromatography[J].Journal of Zhejiang Sci-Tech University,2014,31-32(自科6):599-604.
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碳骨架气相色谱法测定纺织助剂中短链氯化石蜡()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第31-32卷
期数:
2014年自科6期
页码:
599-604
栏目:
(自科)纺织与服装工程
出版日期:
2014-11-10

文章信息/Info

Title:
Measurement of Short Chain Chlorinated Paraffins in Textile Assistant with Carbon Skeleton Gas Chromatography
文章编号:
1673-3851 (2014) 06-0599-06
作者:
李艳 吴俭俭 刘海山 吴刚 姜瑞妹 吕汪洋 陈海相
1. 浙江理工大学, a. 先进纺织材料与制备技术教育部重点实验室; b. 生态染整技术教育部工程研究中心, 杭州 310018;2. 浙江省检验检疫科学技术研究院, 杭州 310016
Author(s):
LI Yan WU Jianjian LIU Haishan WU Gang JIANG Ruimei L Wangyang CHEN Haixiang
1a. Key Laboratory for Advanced Textile Materials and Manufacturing Technology,Ministry of Education; 1b. Engineering Research Center for Eco Dyeing & Finishing of Textiles,Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China;2. Zhejiang Academy of Science & Technology for Inspection & Quarantine, Hangzhou 310016, China
关键词:
短链氯化石蜡 碳骨架 气相色谱法 纺织助剂 磺化
分类号:
O657.7;TS101.9
文献标志码:
A
摘要:
研究碳骨架气相色谱测定纺织助剂中短链氯化石蜡的方法。短链氯化石蜡在钯催化剂作用下发生脱氯氢化被还原成相应的烷烃,重点研究了催化氢化效率的影响因素,采用外标法定量纺织助剂中短链氯化石蜡总量。针对成分复杂的纺织助剂,建立了浓硫酸磺化和弗罗里硅土小柱净化的样品前处理方法。结果表明:该方法定量限为20 mg/kg,平均加标回收率在81.9%~92.8%,相对标准偏差(RSD)小于5%。

参考文献/References:

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[5] Bayen S, Obbard J P, Thomas G O. Chlorinated paraffins: a review of analysis and environmental occurrence[J]. Environment International, 2006, 32(7): 915-929.
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[7] 袁博, 王亚韡, 傅建捷, 等. 氯化石蜡分析方法的研究及土壤样品中氯化石蜡的测定[J]. 科学通报, 2010, 55(19) : 1879-1885.
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[12] Koh I O, Rotard W, Thiemann W H P. Analysis of chlorinated paraffins in cutting fluids and sealing materials by carbon skeleton reaction gas chromatography[J]. Chemosphere, 2002, 47(2): 219-227.
[13] Hussy I, Webster L, Russell M, et al. Determination of chlorinated paraffins in sediments from the Firth of Clyde by gas chromatography with electron capture negative ionisation mass spectrometry and carbon skeleton analysis by gas chromatography with flame ionisation detection[J]. Chemosphere, 2012, 88(3): 292-299.
[14] Rotard W, Mailahn W, Kuhn S, et al. Analyse von chlorparaffinen in sediment, Muscheln, Krabben aus der Umgebung einer Produktionsanlage[J]. UmedInfo, 1998, 7: 19-22.

备注/Memo

备注/Memo:
收稿日期: 2013-12-05
基金项目: 国家自然科学基金项目(51103133);国家质检总局项目(2010IK197);浙江省重中之重(一级)学科资助
作者简介: 李艳(1989-),女,河南商丘人,硕士研究生,主要从事生态纺织品的研究
通信作者: 陈海相,E-mail:ecotes@126.com
更新日期/Last Update: 2014-11-19