|本期目录/Table of Contents|

[1]刘波,王路峰,吴亚舟,等.同轴静电纺丝技术制备PVA@TiO 2纳米纤维及光催化性能研究[J].浙江理工大学学报,2014,31-32(自科2):160-164.
 LIU Bo,WANG Lu feng,WU Ya zhou,et al.Preparation of PVA@TiO 2 Nanofiber by Coaxial Electrospinning Technique and Study of Its Photocatalytic Performance[J].Journal of Zhejiang Sci-Tech University,2014,31-32(自科2):160-164.
点击复制

同轴静电纺丝技术制备PVA@TiO 2纳米纤维及光催化性能研究()
分享到:

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第31-32卷
期数:
2014年自科2期
页码:
160-164
栏目:
(自科)纺织与服装工程
出版日期:
2014-03-10

文章信息/Info

Title:
Preparation of PVA@TiO 2 Nanofiber by Coaxial Electrospinning Technique and Study of Its Photocatalytic Performance
文章编号:
1673-3851 (2014) 02-0160-05
作者:
刘波 王路峰 吴亚舟 王晟 王騊
浙江理工大学先进纺织材料与制备技术教育部重点实验室, 杭州 310018
Author(s):
LIU Bo WANG Lu feng WU Ya zhou WANG Sheng WANG Tao
Key Laboratory of Advanced Textile Materials and Manufacturing Technology,Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
同轴静电纺丝 二氧化钛 聚乙烯醇 光催化
分类号:
TQ426.8
文献标志码:
A
摘要:
采用同轴静电纺丝技术,以二氧化钛(TiO 2)水溶液为壳层、聚乙烯醇(PVA)水溶液为芯层进行同轴静电纺丝,成功制备出了PVA@TiO 2纳米纤维光催化材料。通过热重差热分析(TG DTA)、X射线衍射、扫描电镜对样品进行了表征。结果显示:TiO2纳米粒子的负载量高达91%,是同类方法的2倍之多,同时具有良好的负载牢固的性能;研究了其在紫外光照射下光催化降解罗丹明B的能力,实验表明,20 mL的1×10 -5  mol/L罗丹明B溶液在10 min内完全降解。

参考文献/References:

[1] Wang Z Y, Zhang F B, Zhang Q C. Development of supported TiO 2 photocatalysts[J]. Chem Ind Eng Prog, 2004, 21(4): 248-253.
[2] Moon J, Yun C Y, Chung K W, et al. Photocatalytic activation of TiO 2 under visible light using Acid Red 44[J]. Catal Today, 2003, 87(2): 77-86.
[3] Tavares C J, Marques S M, Viseu T, et al. Enhancement in the Photocatalytic nature of nitrogen doped PVD grown titanium dioxide thin films[J]. J Appl Phys, 2009, 106(11): 113535.
[4] 杨辉, 申乾宏, 高基伟. 酞菁敏化混晶TiO 2薄膜的低温制备及其对罗丹明B的催化降解[J]. 催化学报, 2007, 28(12): 1072-1076.
[5] Ikeda S, Kowata Y, Ikeue K, et al. Asyrmnetrically modified titanium(IV)oxide particles having bothhydrophobic and hydrophilic parts of their surfaces for liquidliquid dualphase photocatalytie reactions[J]. Appl Catal A: General, 2004, 265: 69-74.
[6] Rachel A, Subrahmanyam M, Boule P. Comparison of photocatalytic effieieneies of TiO 2 in suspended and immobilized form for the photocatalytic degradation of nitrobenzenesulfonic acids[J]. Appl Catalysis B: Environmental, 2002, 37(4): 301-308.
[7] Kaariainen M L, Kaariainen T O, Cameron D C. Titanium dioxide thin films, their structure and its effect on their photoactivity and photoeatalytic properties[J]. Thin Solid Films, 2009, 517(24): 6666-6670.
[8] Lopez A, Acosta D, Martinez A I, et al. Nanostructured low crystallized titanium dioxide thin films with good photocatalytic activity[J]. Powder Technol, 2010, 202(1): 111-117.
[9] 李山山, 何素文, 胡祖明. 静电纺丝的研究进展[J]. 合成纤维工业, 2009, 32(4): 44-48.
[10] Hou X G, Gu X N, Hu Y, et al. Enhanced Pt/TiO2 thin films prepared by electron beam irradiation[J]. Nucl Instrum Methods Phys Res: Sect B, 2006, 251(2): 429-434.
[11] Zhu Y, Zhang L, Wang L, et al. The preparation and chemical structure of TiO 2 film photocatalysts supported on stainless steel substrates via the sol gel method[J]. J Mater Chem, 2001, 11: 1864-1868.
[12] Tran T H, Nosaka A Y, Nosaka Y. Adsorption and decomposition of a dipeptide (Ala Trp) in TiO 2 photocatalytic systems[J]. J Photoch Photobio A, 2007, 192(2): 105-113.
[13] 丁源维, 王騊, 姚菊明, 等. 静电纺制备TiO 2/PVA复合纳米纤维及其光催化性能研究[J]. 浙江理工大学学报, 2013, 30(1) : 30-35.

相似文献/References:

[1]王栋良,王騊,王晟. Pt/TiO2纳米管水热还原制备及其光催化性能研究[J].浙江理工大学学报,2011,28(04):575.
 WANG Dong liang,WANG Tao,WANG Sheng. Hydrothermal Preparation of Pt/TiO2 Nanotubes and Its Photocatalytic Activity in Generating CO2[J].Journal of Zhejiang Sci-Tech University,2011,28(自科2):575.
[2]徐友峰,李文华,陈丽娟,等.核壳中空二氧化钛光催化载体的制备及其光催化性能研究[J].浙江理工大学学报,2013,30(06):819.
 XU You feng,LI Wen hua,CHEN Li juan,et al.Research on Preparation and Photocatalytic Performance ofPhotocatalytic Carrier of Titanium Dioxide in Nuclear Shell Hollow[J].Journal of Zhejiang Sci-Tech University,2013,30(自科2):819.
[3]欧阳申珅,王騊,王晟.LSS法制备TiO 2球形晶体及机理研究[J].浙江理工大学学报,2014,31-32(自科6):655.
 OUYANG Shen shen,WANG Tao,WANG Sheng.Research on Preparation of TiO 2 Spherical Crystal with LSS Method and Its Mechanism[J].Journal of Zhejiang Sci-Tech University,2014,31-32(自科2):655.
[4]张海涛,骆菁菁,邢同海,等.SF/PCL-BSA皮芯结构纳米纤维支架的制备及缓释性能[J].浙江理工大学学报,2015,33-34(自科6):766.
 ZHANG Hai tao,LUO Jing jing,XING Tong hai,et al.Preparation and Slow Release Properties of Nanofibrous Scaffolds with SF/PCLBSA Sheathcore Structure[J].Journal of Zhejiang Sci-Tech University,2015,33-34(自科2):766.

备注/Memo

备注/Memo:
收稿日期: 2013-09-30
基金项目: 国家自然科学基金(31070888,21103152);浙江省自然科学基金资项目(Y4080392);浙江省创新团队项目(2011R50003);浙江理工大学材料科学与工程研究生教育创新示范基地(编号3)
作者简介: 刘波(1988-),男,河南上蔡人,硕士研究生,主要从事纳米催化剂的研究
通信作者: 王晟,E-mail:wangsheng571@hotmail.com
更新日期/Last Update: 2014-04-15