|本期目录/Table of Contents|

[1]董晓玲,李婷婷,陈丽江.熔融碳酸盐燃料电池多孔镍阴极的制备及修饰[J].浙江理工大学学报,2013,30(05):703-707.
 DONG Xiao ling,LI Ting ting,CHEN Li jiang.Preparation and Modification of Porous Nickel Cathode for Molten Carbonate Fuel Cell[J].Journal of Zhejiang Sci-Tech University,2013,30(05):703-707.
点击复制

熔融碳酸盐燃料电池多孔镍阴极的制备及修饰()
分享到:

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第30卷
期数:
2013年05期
页码:
703-707
栏目:
出版日期:
2013-09-10

文章信息/Info

Title:
Preparation and Modification of Porous Nickel Cathode for Molten Carbonate Fuel Cell
文章编号:
1673-3851 (2013) 05-0703-05
作者:
董晓玲 李婷婷 陈丽江
浙江理工大学理学院, 杭州 310018
Author(s):
DONG Xiao ling LI Ting ting CHEN Li jiang
School of Sciences, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
熔融碳酸盐燃料电池 多孔镍阴极 制备 修饰
分类号:
TM911.47
文献标志码:
A
摘要:
以羰基Ni粉为原料,加入造孔剂、增塑剂(PEG)和粘合剂(PVB)等充分混合制成Ni基体阴极素坯。将素坯在一定温度和气氛下烧结获得多孔镍基体阴极。采用XRD及SEM等技术对烧结后的多孔镍基阴极材料的成分及形貌等进行表征分析,筛选了较佳的造孔剂,并优化了烧结工艺,获得具有良好孔结构的多孔镍基体阴极材料。并进一步采用电泳沉积技术(EPD)对所制备的多孔镍基体阴极进行修饰,即在其表面沉积纳米颗粒层,获得的复合阴极材料保持了镍基体阴极的多孔结构且在模拟MCFC启动阶段运行条件下表现出良好的抗形变和抗溶解性能。

参考文献/References:

[1] Chen L J, Lin C J, Cheng X, et al. A study on the deformation of porous nickel oxide cathode materials in MCFC[J]. Solid State Ionics, 2002, 148(3/4): 539-544.
[2] Baumgartner, Charles E, Kenneth P, et al. Fabrication and characterization of porous nickel oxide cathodes for use in molten carbonate fuel cells[J]. Am Ceram Soc Bull, 1985, 64(4): 593-597.
[3] 李新法, 沈百拴, 陈建勋. PVB的热行为及其热降解过程[J]. 河南科学, 1994, 12(2): 111-115.
[4] Seo J J, Kuk S T, Kim K. Thermal decompostion of PVB(polyvinyl butyral) binder in the matix and electrolyte of molten carbonate fuel cells[J]. J Power Sources, 1997, 69(1-2): 61-67.
[5] 刘霞, 姜春燕, 郑艳菊. A2+B3型超支化芳香脂肪型聚酰胺的合成及其表征[J]. 高分子通报, 2010, (3): 35-39.
[6] 朱荣淑, 郭明新, 欧阳峰. 单一金属氧化物同时催化去除碳颗粒和NOx[J]. 物理化学学报, 2009, 25(1): 131-136.
[7] 张惠英, 孙吉昌. 核燃料热行为的热分析研究[J]. 核动力工程, 1992, 13(3): 86-88.
[8] Daza L, Rangel C M, Baranda J, et al. Modified nickel oxides as cathode materials for MCFC [J]. J Power Sources, 2000, 86(1-2): 329-333.
[9] Soler J, Gonzalez T, Escudero M J, et al. Endurance test on a single cell of a novel cathode material for MCFC[J]. J Power Sources, 2002, 106(1/2): 189-195.
[10] Huang B, Chen G, Li F, et al. Study of NiO cathode modified by rare earth oxide additive for MCFC by electrochemical impedance spectroscopy[J]. Electrochimi. Acta, 2004, 49(28): 5055-5068.
[11] Wijayasinghe A, Bergman B, Lagergren C. A study on LiCO2-rich cathode materials for the MCFC based on the LiCoO2-LiFeO2-NiO ternary system[J]. Electrochimi. Acta, 2004, 49(26): 4709-4717.
[12] Ringued A, Wijayasinghe A, Albin V, et al. Solubility and electrochemical studies of LiFeO2-LiCoO2-NiO materials for the MCFC cathode application[J]. J Power Sources, 2006, 160(2): 789-795.
[13] Chen L J, Liu H H, Dong X L, et al. Novel compositebased cathodes for Molten Carbonate Fuel Cells by electrochemical multicomponent modification[J]. Funct Mater Lett, 2011, 4(4): 383-387.
[14] Chen L J, Liu H H, Dong X L, et al. Preparation and property of a compositebased cathode for Molten Carbonate Fuel Cells[J]. Chin J Inorg Chem, 2012, 28(3): 584-590.

相似文献/References:

[1]李婷婷,柴丰涛,陈丽江,等.两步法合成MCFC复合阴极及其性能研究[J].浙江理工大学学报,2014,31-32(自科4):393.
 LI Ting  ting,CHAI Feng tao,CHEN Li jiang,et al.Two step Synthesis of Composite Cathodes of MCFC and Study on Its Performance[J].Journal of Zhejiang Sci-Tech University,2014,31-32(05):393.

备注/Memo

备注/Memo:
收稿日期: 2012-12-28
基金项目: 浙江省自然科学基金(Y4100191)
作者简介: 董晓玲(1986-),女,山东青岛人,硕士研究生,主要从事锂离子电池和燃料电池相关材料分子设计方面研究。
通信作者:陈丽江,电子邮箱:janelchen@yahoo.com.cn
更新日期/Last Update: 2013-10-22