|本期目录/Table of Contents|

[1]袁艳,张睿,戚栋明,等. 纳米SiO2分散乙醇介质过程中的解团聚行为[J].浙江理工大学学报,2011,28(04):485-489.
　YUAN Yan,ZHANG Rui,QI Dong ming,et al. Deaggregation Behavior in the Dispersion Process of Silica Soft Aggregation into Ethanol Media[J].Journal of Zhejiang Sci-Tech University,2011,28(04):485-489.
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 纳米SiO2分散乙醇介质过程中的解团聚行为()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第28卷
期数:
2011年04期
页码:
485-489
栏目:
(自科)纺织与服装工程
出版日期:
2011-08-31

文章信息/Info

Title:
 Deaggregation Behavior in the Dispersion Process of Silica Soft Aggregation into Ethanol Media
文章编号:
16733851 (2011) 04048505
作者:
 袁艳;  张睿;  戚栋明;  邵建中
 浙江理工大学生态染整技术教育部工程研究中心， 杭州 310018
Author(s):
 YUAN Yan;  ZHANG Rui;  QI Dongming;  SHAO Jianzhong
 Engineering Research Center of EcoDyeing & Finishing of Textiles（Zhejiang SciTech University）, Ministry of Education, Hangzhou 310018, China
关键词:
 ; SiO2;  偶联改性;  乙醇分散液;  分散性
分类号:
TB34
文献标志码:
A
摘要:
    将纳米SiO2粉体通过高速剪切、强力超声和3(甲基丙烯酰氧)丙基三甲氧基硅烷(MPS)偶联改性等手段分散于乙醇介质中，通过粒径分析(DLS)和透射电镜(TEM)考察了乙醇中SiO2的分散状态，通过红外光谱(FTIR)和热重分析(TG)表征了SiO2颗粒表面的偶联情况。发现超声分散对SiO2聚集体具有较好的解软团聚作用，但这种解团聚效果会随放置时间的延长而逐渐失效。SiO2颗粒表面偶联2%~5%的MPS后，可有效提高解软团聚效果的稳定性，相应的SiO2可在乙醇分散液中达到亚微米级的稳定均匀分散。

参考文献/References:

 ［1］ Bauer F, Glasel H J, Hartmann E, et al. Functionalized inorganic/organic nanocomposites as new basic raw materials for adhesives and sealants［J］. Int J Adhesion & Adhesives, 2004, 24: 519.
［2］ 林鹤鸣, 吕娜娜, 戚栋明, 等. PBA/TiO2接枝复合整理剂及其整理棉织物的抗紫外线性能［J］. 纺织学报, 2009, 30(4): 8589.
［3］ 蒋利军, 符新, 李光, 等. 纳米二氧化硅复合材料的应用研究进展［J］. 热带农业科学, 2007, 27(6): 6467.
［4］ Zou H, Wu S S, Shen J. Polymer/silica nanocomposites: preparation, characterization, properties, and applications［J］. Chem Rev, 2008, 108(9): 38923957.
［5］ 雷琳, 吕娜娜, 吴明华, 等. 水相介质中纳米TiO2粒子软团聚体的解团聚［J］. 化工学报, 2009, 60(12): 31593164.
［6］ Nalwa H S. Handbook of OrganicInorganic Hybrid Materials and Nanocomposites［M］. California: Ameican Scientific Publishers, 2003: 113150.
［7］ Mackay M E, Tuteja A, Duxbury P M, et al. General strategies for nanoparticle dispersion［J］. Science, 2006, 311: 17401743.
［8］ Sergey L, Sarat K S, Avraam I, et al. Ultrasound aided extrusion process for preparation of polyolefinclay nanocomposites［J］. Institute of Polymer Engineering, 2008, 48(8): 15841591.
［9］ Katsikis N, Zahradnik F, Helmschrott A, et al. Thermal stability of poly(methyl methacrylate)/silica nanoand microcomposites as investigated by dynamicmechanical experiments［J］. Polymer Degradation and Stability, 2007, 11(92): 19661976.
［10］ Kerner D, Meyer J. Surfacemodified pyrogenic titanium dioxide, used in cosmetics eg sunprotection agents, is treated with armnoniumfunctional silane［P］. DE: 19929845, 20010913.
［11］ 吴明华, 吕娜娜, 雷琳, 等. 纳米TiO2粒子静电吸附引发剂及其原位锚固丙烯酸丁酯聚合［J］. 高分子学报, 2009(5): 445450.
［12］ Cai A Y, Zhang S L, Zhu A P, et al. Synthesis and properties of polystyrenegmSiO2 filled polypropylene nanocomposites［J］. Polym Composite, 2009, 31(5): 807815.
［13］ Teofil J, Andrzej K. Influence of silane coupling agents on surface properties of precipitated silicas［J］. Applied Surface Science, 2001, 172: 1832.
［14］ 戚栋明, 包永忠, 黄志明, 等. 甲基丙烯酸甲酯/纳米SiO2粒子分散液的细乳化和细乳液聚合［J］. 高分子学报, 2006(6): 774778.
［15］ 姜立忠, 战佳宇, 武德珍, 等. 甲基丙烯酰氧基三甲氧基硅烷改性SiO2的制备［J］. 北京化工大学学报, 2007, 34(3): 287289.

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备注/Memo

备注/Memo:
 收稿日期： 2010-08-19
基金项目： 国家自然科学基金项目(50803058)；浙江省科研计划项目(2009C31089)；浙江省新苗人才计划项目；浙江省自然科学基金项目(Y4100221)
作者简介： 袁艳(1985-)，女，浙江舟山人，硕士研究生，主要研究方向为新型纺织化学品开发。
通讯作者： 邵建中，电子邮箱：jshao198@yahoo.com.cn
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