|本期目录/Table of Contents|

[1]王宁宁,高峰,陈智杰,等.聚丙烯酸酯/聚氨酯/SiO 2纳米复合黏合剂的细乳液法制备及其粘接性能[J].浙江理工大学学报,2019,41-42(自科三):308-313.
　WANG Ningning,GAO Feng,CHEN Zhijie,et al.Preparation of polyacrylate/polyurethane/SiO2 nanocomposite adhesives  through miniemulsion polymerization and their bonding performance[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科三):308-313.
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聚丙烯酸酯/聚氨酯/SiO 2纳米复合黏合剂的细乳液法制备及其粘接性能()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第41-42卷
期数:
2019年自科三期
页码:
308-313
栏目:
出版日期:
2019-06-23

文章信息/Info

Title:
Preparation of polyacrylate/polyurethane/SiO2 nanocomposite adhesives  through miniemulsion polymerization and their bonding performance
文章编号:
1673-3851 (2019) 05-0308-06
作者:
王宁宁; 高峰; 陈智杰; 叶凤莲; 戚栋明; 曹志海
1.浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州，310018；2.浙江海泰新材料有限公司，浙江 金华，321100
Author(s):
WANG Ningning;  GAO Feng;  CHEN Zhijie;  YE Fenglian;  QI Dongming;  CAO Zhihai
1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China; 2. Zhejiang Haitai New Materials Co., Ltd., Jinhua 32100, China
关键词:
细乳液聚合; 黏合剂; 聚丙烯酸酯; 聚氨酯; 粘接性能
分类号:
TQ433
文献标志码:
A
摘要:
以表面乙烯基修饰的SiO2纳米粒子为无机组分，以丙烯酸异辛酯、甲基丙烯酸甲酯、甲基丙烯酸和甲基丙烯酸2羟乙酯为自由基共聚单体，以异氟尔酮二异氰酸酯和聚己内脂二醇为聚氨酯（PU）预聚单体，采用细乳液聚合法一步制备聚丙烯酸酯（PAcr）/PU/SiO2纳米复合黏合剂，同时以细乳液聚合法制备的PAcr和PAcr/PU黏合剂作为参照。利用动态光散射、红外光谱、力学性能测试和差示扫描量热等手段对黏合剂的组成、粒子的颗粒特征、粘接性能和热性能等进行表征，系统比较了上述三类黏合剂的差异。结果表明：引入PU和SiO2组分能显著提升黏合剂的粘接性能，PAcr/PU/SiO2纳米复合黏合剂胶膜强度最高，初粘力和剥离力间能达到较好的平衡。

参考文献/References:

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［3］ Daniloska V, Carretero P, Tomovska R, et al. Highperformance adhesives resulting from spontaneous formation of nanogels within miniemulsion particles［J］. ACS Applied Materials & Interfaces, 2014, 6(5): 3559-3567.［4］ Udagama R, DegrandiContraires E, Creton C, et al. Synthesis of acrylicpolyurethane hybrid latexes by miniemulsion polymerization and their pressuresensitive adhesive applications［J］. Macromolecules, 2011, 44(8): 2632-2642.
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［7］ Daniloska V, Keddie J L, Asua J M, et al. MoS2 nanoplatelet fillers for enhancement of the properties of waterborne pressuresensitive adhesives［J］. ACS Applied Materials & Interfaces, 2014, 6(24): 22640-22648.［8］ Diaconu G, Micusik M, Bonnefond A, et al. Macroinitiator and macromonomer modified montmorillonite for the synthesis of acrylic/MMT nanocomposite latexes［J］. Macromolecules, 2009, 42(9): 3316-3325.
［9］ 吴立霞,许戈文,黄毅萍.聚氨酯丙烯酸酯/纳米SiO2核壳型乳液的合成及表征［J］.精细化工,2013,30(10):1086-1091.
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备注/Memo

备注/Memo:
收稿日期： 2018-09-29
网络出版日期： 2018-11-02
基金项目： 国家自然科学基金项目（51573168）；浙江省自然科学基金项目（LY16E030006）
作者简介： 王宁宁（1991-），女，山西运城人，硕士研究生，主要从事有机无机复合材料制备及表征方面的研究
通信作者： 曹志海，E-mail:zhcao@zstu.edu.cn
更新日期/Last Update: 2019-05-29