|本期目录/Table of Contents|

[1]毛贻静,潘栋宇,张潇天,等.原位成核生长法制备草莓状多级结构聚合物有机硅复合微球[J].浙江理工大学学报,2019,41-42(自科二):174-181.
　MAO Yijing,PAN Dongyu,ZHANG Xiaotian,et al.Preparation of raspberry like polystyrene/organosilica composite microspheres  with hierarchical structure by insitu nucleation and growth method[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科二):174-181.
点击复制

原位成核生长法制备草莓状多级结构聚合物有机硅复合微球()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第41-42卷
期数:
2019年自科二期
页码:
174-181
栏目:
出版日期:
2019-04-23

文章信息/Info

Title:
Preparation of raspberry like polystyrene/organosilica composite microspheres  with hierarchical structure by insitu nucleation and growth method
文章编号:
1673-3851 (2019)03-0174-08
作者:
毛贻静; 潘栋宇; 张潇天; 曹志海; 戚栋明; 孙阳艺
浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州 310018
Author(s):
MAO Yijing;  PAN Dongyu;  ZHANG Xiaotian;  CAO Zhihai;  QI Dongming;  SUN Yangyi
Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
原位成核生长; 草莓状; 有机硅; 复合微球; 动力学可控
分类号:
O6
文献标志码:
A
摘要:
报道了通过原位成核生长法高效构筑草莓状多级结构聚合物有机硅复合微球的方法。以聚乙烯基吡咯烷酮（PVP）为稳定剂制备得到的粒径均一的聚苯乙烯（PS）微球为中心核粒子，吸附自组装的十六烷基三甲基溴化铵（CTAB）胶束后，与水解过的硅烷偶联剂（BTEE/TEOS）混合，得到草莓状的PS@oSiO2复合微球。通过引入CTAB胶束对核种子粒子进行改性及对后续生长有机硅进行预水解，通过调控CTAB胶束液用量及有机硅水解缩合反应条件，可有效控制PS微球和有机硅前驱物之间的反应动力学，最终可控制备表面凸起小粒子粒径及覆盖度可调的草莓状PS@oSiO2复合微球。该研究不仅有利于了解原位成核生长法制备草莓状复合微球的形成机制，还对开发高性能浸润性表界面具有重要意义。

参考文献/References:

［1］ Mansaray H B, Rowe A D, Phillips N, et al. Modelling fundamental areneborane contacts: Spontaneous formation of a dibromoborenium cation driven by interaction between a borane Lewis acid and an arene π system［J］. Chemical Communications, 2011, 47(45): 12295-12297.
［2］ Ming W, Wu D, van Benthem R, et al. Superhydrophobic films from raspberrylike particles［J］. Nano Letters, 2005, 5(11): 2298-2301.
［3］ Qian Z, Zhang Z C, Song L Y, et al. A novel approach to raspberrylike particles for superhydrophobic material［J］. Journal of Materials Chemistry, 2009, 19(9): 1297-1304.
［4］ Du X, Liu X M, Chen H M, et al. Facile fabrication of raspberrylike composite nanoparticles and their application as building blocks for constructing superhydrophilic coatings［J］. The Journal of Physical Chemistry C, 2009, 113(21): 9063-9070.
［5］ Chen M, Wu L M, Zhou S X, et al. Synthesis of raspberrylike PMMA/SiO2 nanocomposite particles via a surfactantfree method［J］. Macromolecules, 2004, 37(25): 9613-9619.
［6］ Chen M, Zhou S X, You B, et al. A novel preparation method of raspberrylike PMMA/SiO2 hybrid microspheres［J］. Macromolecules, 2005, 38(15): 6411-6417.
［7］ Fan X L, Jia X K, Liu Y, et al. Tunable wettability of hierarchical structured coatings derived from onestep synthesized raspberrylike poly (styreneacrylic acid) particles［J］. Polymer Chemistry, 2015, 6(5): 703-713.
［8］ Yu M G, Wang Q, Zhang M, et al. Facile fabrication of raspberrylike composite microspheres for the construction of superhydrophobic films and applications in highly efficient oilwater separation［J］. RSC Advances, 2017, 7(63): 39471-39479.
［9］ Zhang X T, Sun Y Y, Mao Y J, et al. Controllable synthesis of raspberrylike PSSiO2 nanocomposite particles via pickering emulsion polymerization［J］. RSC Advances, 2018, 8(7): 3910-3918.
［10］ Yang Y N, Wan J J, Niu Y T, et al. Structuredependent and glutathioneresponsive biodegradable dendritic mesoporous organosilica nanoparticles for safe protein delivery［J］. Chemistry of Materials, 2016, 28(24): 9008-9016.

相似文献/References:

[1]毛贻静,潘栋宇,张潇天,等.原位成核生长法制备草莓状多级结构聚合物-有机硅复合微球[J].浙江理工大学学报,2019,41-42(自科二):174.
　MAO Yijing,PAN Dongyu,ZHANG Xiaotian,et al.Preparation of raspberrylike polystyrene/organosilica composite microspheres with hierarchical structure by insitu nucleation and growth method[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科二):174.

备注/Memo

备注/Memo:
作者简介： 毛贻静(1993-)，女，河南新乡人，硕士研究生，主要从事聚合物微球制备与表征方面的研究。
通信作者： 孙阳艺，E-mail：yangyisun@zstu.edu.cn
更新日期/Last Update: 2019-03-19