|本期目录/Table of Contents|

[1]梁启迪,谢文兴,张俊华.高铁酸钾稳定剂对HMF氧化产生FDCA的影响研究[J].浙江理工大学学报,2018,39-40(自科6):692-697.
　LIANG Qidi,XIE Wenxing,ZHANG Junhua.Effect of potassium ferrate stabilizer on the generation of FDCA by HMF oxidation[J].Journal of Zhejiang Sci-Tech University,2018,39-40(自科6):692-697.
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高铁酸钾稳定剂对HMF氧化产生FDCA的影响研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第39-40卷
期数:
2018年自科6期
页码:
692-697
栏目:
出版日期:
2018-11-10

文章信息/Info

Title:
Effect of potassium ferrate stabilizer on the generation of FDCA by HMF oxidation
文章编号:
1673-3851 (2018) 11-0692-06
作者:
梁启迪; 谢文兴; 张俊华
浙江理工大学材料与纺织学院，杭州 310018
Author(s):
LIANG Qidi;  XIE Wenxing;  ZHANG Junhua
College of Material and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
5-羟甲基糠醛; 2; 5-呋喃二甲酸; 高铁酸钾; 氧化; 稳定剂
分类号:
TQ314.22
文献标志码:
A
摘要:
通过构建高铁酸钾/氢氧化钠磷酸氢二钾的反应体系，研究NaOH和K-2HPO-4等高铁酸钾稳定剂用量对5羟甲基糠醛催化氧化为2,5呋喃二甲酸的影响。结果表明：当体系中NaOH和K2HPO-4用量分别为1.6 mol/L和0.4 mol/L时，高铁酸钾/氢氧化钠磷酸氢二钾体系具有最佳的氧化效果，5羟甲基糠醛在25 ℃的温度下反应15 min，2,5-呋喃二甲酸的得率可达到82.4%；通过对NaCl、KCl、CaCl2、Mg(OH)2、Al(OH)3、MnO2、Fe2O3、Fe(OH)3及CuO等高铁酸钾助氧化金属化合物的研究，发现Fe2O3和Fe(OH)3等两种金属化合物具有较好的助氧化效果，且Fe(OH)3表现出最佳的助氧化活性，当其用量为1 mmol/L时，2,5呋喃二甲酸的得率可高达91.7%；通过对2,5呋喃二甲酸及其标准品的红外及核磁分析，确定2,5呋喃二甲酸的结构。

参考文献/References:

［1］ Dutta S, De S, Saha B. A brief summary of the synthesis of polyester buildingblock chemicals and biofuels from 5 hydroxymethylfurfural［J］. Chempluschem,2012,77(4):259-272.
［2］ Sousa A F, Matos M, Freire C S R, et al. New copolyesters derived from terephthalic and 2,5furandicarboxylic acids: A step forward in the development of biobased polyesters［J］. Polymer,2013.54(2):513-519.
［3］ Eerhart A J J E, Faaij A P C, Patel M K. Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance［J］. Energy & Environmental Science,2012,5(4):6407-6422.
［4］ Ma J, Yu X, Xu J, et al. Synthesis and crystallinity of poly(butylene 2,5furandicarboxylate)［J］. Polymer,2012,53(19):4145-4151.
［5］ Casanova, O, Iborra S, Corma A. Biomass into chemicals: Aerobic oxidation of 5hydroxymethyl2furfural into 2,5furandicarboxylic acid with gold nanoparticle catalysts［J］. ChemSusChem,2009,2(12):1138-1144.
［6］ Gupta N K, Nishimura S, Takagaki A, et al. Hydrotalcite  supported goldnanoparticlecatalyzed highly efficient basefree aqueous oxidation of 5hydroxymethylfurfural into 2, 5furandicarboxylic acid under atmospheric oxygen pressure［J］. Green Chemistry,2011,13(4):824-827.
［7］ Albonetti S, Pasini T, Lolli A. Selective oxidation of 5hydroxymethyl2furfural over TiO2supported goldcopper catalysts prepared from preformed nanoparticles: Effect of Au/Cu ratio［J］. Catalysis Today,2012,195(1):120-126.
［8］ Boisen A, Christensen T B, Fu W. Process integration for the conversion of glucose to 2,5furandicarboxylic acid［J］. Chemical Engineering Research and Design,2009,87(9):1318-1327.
［9］ Davis S E, Houk L R, Tamargo E C. Oxidation of 5hydroxymethylfurfural over supported Pt, Pd and Au catalysts［J］. Catalysis Today,2011,160(1):55-60.
［10］ Davis S E, Zope B N, Davis R J. On the mechanism of selective oxidation of 5hydroxymethylfurfural to 2,5furandicarboxylic acid over supported Pt and Au catalysts［J］. Green Chemistry,2012,14(1):143-147.

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备注/Memo

备注/Memo:
收稿日期： 2018-01-02
网络出版日期： 2018-05-14
基金项目： 国家自然科学基金项目(21406208)；浙江省自然科学基金项目(LY17C160008)
作者简介： 梁启迪(1993-)，男，安徽六安人，硕士研究生，主要从事生物质能源化工方面的研究
通信作者： 张俊华，E-mail：zhangjh@zstu.edu.cn
更新日期/Last Update: 2018-11-09