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[1]尤会敏,赵彦英.2,3,9,10,16,17,23,24 八羧基酞菁铁敏化 TiO 2的合成及光催化性能研究[J].浙江理工大学学报,2016,35-36(自科5):781-787.
 YOU Huimin,ZHAO Yanying.Study on Synthesis and Photocatalytic Property of  FePc(COOH) 8 Sensitized TiO 2[J].Journal of Zhejiang Sci-Tech University,2016,35-36(自科5):781-787.
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2,3,9,10,16,17,23,24 八羧基酞菁铁敏化 TiO 2的合成及光催化性能研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第35-36卷
期数:
2016年自科5期
页码:
781-787
栏目:
出版日期:
2016-09-10

文章信息/Info

Title:
Study on Synthesis and Photocatalytic Property of  FePc(COOH) 8 Sensitized TiO 2
文章编号:
1673-3851 (2016) 05-0781-07
作者:
尤会敏赵彦英
浙江理工大学理学院,杭州 310018
Author(s):
YOU Huimin ZHAO Yanying
School of Science, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
八羧基酞菁敏化二氧化钛可见光催化染料降解一级反应动力学
分类号:
TB34
文献标志码:
A
摘要:
将固体熔融法合成的2,3,9,10,16,17,23,24八羧基酞菁铁(FePc(COOH)8)敏化二氧化钛制备了酞菁铁二氧化钛催化剂。通过UV、FIIR、PL、XRD、DRS、XPS和N2吸附脱附等一系列实验方法对催化剂进行了表征和催化性能分析。在可见光条件下研究了八羧基酞菁铁(FePc(COOH)8)敏化的TiO2催化剂对亚甲基蓝(MB)、罗丹明B(RB)、中性红(NR)、酸性红(AR)和孔雀石绿(MG)水溶液的降解动力学。研究结果表明在t=100 min 时,此光催化剂降解这四种有机染料均有良好的效果。染料降解动力学曲线拟合表明此光催化降解过程符合一级化学反应动力学方程,其降解MB、RB、NR、AR和MG动力学常数分别为0.04359、0.03508、0.01901、0.01302 min-1和0.00968 min -1。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期: 2015-12-04
基金项目: 国家自然科学基金项目(21273202, 21473162)
作者简介: 尤会敏(1988-),女,河南商丘人,硕士研究生, 主要从事酞菁类化合物的合成及光催化性能方面的研究
通信作者: 赵彦英,E-mail: yyzhao@zstu.edu.cn
更新日期/Last Update: 2016-10-14