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[1]李嘉,杨继福,张潇天,等.基于中空草莓状微球的超疏水隔热涂层织物制备及性能分析[J].浙江理工大学学报,2022,47-48(自科五):649-657.
　LI Jia,YANG Jifu,ZHANG Xiaotian,et al.Preparation and properties of fabrics with superhydrophobic and  thermal  insulating coating based on hollow  raspberry like microspheres[J].Journal of Zhejiang Sci-Tech University,2022,47-48(自科五):649-657.
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基于中空草莓状微球的超疏水隔热涂层织物制备及性能分析()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第47-48卷
期数:
2022年自科第五期
页码:
649-657
栏目:
出版日期:
2022-09-10

文章信息/Info

Title:
Preparation and properties of fabrics with superhydrophobic and  thermal  insulating coating based on hollow  raspberry like microspheres
文章编号:
1673-3851 (2022) 09-0649-09
作者:
李嘉; 杨继福; 张潇天; 戚栋明; 孙阳艺
浙江理工大学，a.先进纺织材料与制备技术教育部重点实验室；b.绿色低碳染整技术浙江省工程研究中心，杭州 310018
Author(s):
LI Jia; YANG Jifu; ZHANG Xiaotian; QI Dongming; SUN Yangyi
a.MOE Key Laboratory of Advanced Textile Material and Preparation Technology; b.Zhejiang Provincial  Engineering Research Center for Green and Low carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
有机硅; 复合微球; 草莓状结构; 涂层; 超疏水; 隔热
分类号:
O6
文献标志码:
A
摘要:
利用功能纳米粒子对织物进行涂层整理，是实现纺织品功能化的有效途径。利用原位异质成核和生长法，以正电荷的聚苯乙烯（PS）微球为种子，有机硅烷为生长物质前驱物，制备部分中空的草莓状聚苯乙烯@有机硅（PS@oSiO2）复合微球，然后经氟硅烷进一步接枝改性后得到中空结构更加明显的F PS@oSiO2复合微球，最后将其与有机硅树脂（PDMS）简单共混后涂覆到织物表面，制备得到了一种多功能涂层织物。分析草莓复合微球和涂层织物的形貌及组成，考察复合微球中空结构的形成机理，观测涂层织物的表面润湿性和隔热性能，探究微球固含量对涂层织物超疏水性能的影响规律。研究结果表明：制备得到的部分中空的草莓状PS@oSiO2复合微球单分散性良好，氟硅烷可被成功接枝到PS@oSiO2复合微球表面得到F-PS@oSiO2复合微球；在碱性条件下进行热处理时，复合微球中聚合物PS的进一步溶解及迁出是中空结构变得明显的主要原因。当F-PS@oSiO2复合微球质量分数达到1.0%时，涂层织物的接触角可达到155°，对茶水、牛奶、咖啡、橙汁等不同液体保持超疏水特性，同时还具有一定的保温隔热性能。该研究为开发多功能纺织品提供了新的思路和途径。

参考文献/References:

［1］Peng J Y, Zhao X J, Wang W F, et al. Durable selfcleaning surfaces with superhydrophobic and highly oleophobic properties［J］. Langmuir, 2019, 35(25): 8404-8412.

［2］Wang T, Huang L, Liu Y Z, et al. Robust biomimetic hierarchical diamond architecture with a selfcleaning, antibacterial, and antibiofouling surface［J］. ACS Applied Materials & Interfaces, 2020, 12(21): 24432-24441.

［3］Zhang X T, Liu S Q, Salim A, et al. Hierarchical structured multifunctional selfcleaning material with durable superhydrophobicity and photocatalytic functionalities［J］. Small, 2019, 15(34): 1901822.

［4］Bixler G D, Bhushan B. Bioinspired rice leaf and butterfly wing surface structures combining shark skin and lotus effects［J］. Soft Matter, 2012, 8(44): 11271.

［5］Zhang R L, Zhou Z P, Wang Y, et al. Onestep condensation/copolymerization of VTES and DVB for selfassembly bionic superhydrophobic surface coating and study on oilwater separation［J］. Journal of Bionic Engineering, 2021, 18(3): 559-573.

［6］Wan H R, He T T, Ju X Z, et al. Rapid fabrication of superhydrophobic surface on magnesium alloy with excellent corrosionresistant and selfcleaning properties［J］. Bulletin of the Chemical Society of Japan, 2021, 94(3): 961-965.

［7］Sun J T, Cai F, Tao D Z, et al. Enhanced thermal insulation of the hollow glass microsphere/glass fiber fabric textile composite material［J］. Polymers, 2021, 13(4): 505.

［8］Dombrovsky L A, Randrianalisoa J H, Baillis D. Infrared radiative properties of polymer coatings containing hollow microspheres［J］. International Journal of Heat and Mass Transfer, 2007, 50(7/8): 1516-1527.

［9］Sun Y Y, Chen M, Zhou S X, et al. Controllable synthesis and surface wettability of flowershaped silver nanocubeorganosilica hybrid colloidal nanoparticles［J］. ACS Nano, 2015, 9(12): 12513-12520.

［10］Sun Y Y, Chen M, Wang Z B, et al. Facile synthesis of asymmetric Agorganosilica hybrid nanoparticles with tunable morphologies and optical properties［J］. Chemical Communications, 2014, 50(43): 5767-5770.

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相似文献/References:

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　MAO Yijing,PAN Dongyu,ZHANG Xiaotian,et al.Preparation of raspberry like polystyrene/organosilica composite microspheres  with hierarchical structure by insitu nucleation and growth method[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科五):174.
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备注/Memo

备注/Memo:
收稿日期： 2022-03-28
网络出版日期：2022-05-09
基金项目： 国家自然科学基金青年基金项目(51703203)；浙江省自然基金青年基金项目(LQ17E030004)
作者简介： 李嘉(1996-)，男，河南信阳人，硕士研究生，主要从事多功能织物涂层方面的研究
通信作者： 孙阳艺，E-mail：yangyisun@zstu.edu.cn
更新日期/Last Update: 2022-09-07