|本期目录/Table of Contents|

[1]王亚君,宋莉.三角形配位构型碘化亚铜配合物的合成、结构与性质[J].浙江理工大学学报,2019,41-42(自科四):537-543.
 WANG Yajun,SONG Li.Syntheses, structures and properties of cuprous iodide complexes of triangle coordination geometry[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科四):537-543.
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三角形配位构型碘化亚铜配合物的合成、结构与性质()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第41-42卷
期数:
2019年自科四期
页码:
537-543
栏目:
出版日期:
2019-06-20

文章信息/Info

Title:
Syntheses, structures and properties of cuprous iodide complexes of triangle coordination geometry
文章编号:
1673-3851 (2019) 07-0544-07
作者:
王亚君宋莉
浙江理工大学理学院,杭州 310018
Author(s):
WANG Yajun SONG Li
School of Sciences, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
碘化亚铜配合物膦配体三角形配位构型
分类号:
TS195-644
文献标志码:
A
摘要:
对两个新颖的碘化亚铜配合物CuI[2(Dpp)bp]2(配合物1,2(Dpp)bp=二(二苯基膦)联苯)和Cu2(μI)2〖JP〗[TPP(oOCH3)]2瘙簚CH3CN (配合物2,TPP(oOCH3)=三(3甲氧基苯基)膦)的合成、晶体结构和性质进行了研究。配合物1和配合物2分别表现为单核、双核碘化亚铜配合物的结构类型。在配合物1和2的晶体结构中,亚铜原子都表现为不同寻常的近乎平面的三角形配位构型,〖JP2〗推测其原因可能是由于膦配体较大的空间位阻效应所致。两配合物都表现了良好的热稳定性,双核配合物2的热稳定性优于单核配合物1。配合物1和2的紫外可见吸收主要来自于膦配体的ππ*电子吸收跃迁,配合物1和2的能隙值分别为358、321 eV,说明配合物1和2均属于半导体。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2019-02-15
网络出版日期: 2019-04-01
基金项目:浙江省自然科学基金项目(LY16B030009);浙江理工大学521人才计划
作者简介:王亚君(1992-),女,山东德州人,硕士研究生,主要从事配合物功能材料方面的研究
通信作者:宋莉,E-mail:songli@zstu.edu.cn
更新日期/Last Update: 2019-09-16