|本期目录/Table of Contents|

[1]王杰,薛敏.1,4-二甲氧基柱[5]芳烃醌类的环氧衍生化[J].浙江理工大学学报,2019,41-42(自科一):127-133.
 WANG Jie,XUE Min.Epoxidation of 1,4-dimethoxypillar[5]arenequinones[J].Journal of Zhejiang Sci-Tech University,2019,41-42(自科一):127-133.
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1,4-二甲氧基柱[5]芳烃醌类的环氧衍生化()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第41-42卷
期数:
2019年自科一期
页码:
127-133
栏目:
出版日期:
2018-12-15

文章信息/Info

Title:
Epoxidation of 1,4-dimethoxypillar[5]arenequinones
文章编号:
1673-3851 (2019) 01-0127-07
作者:
王杰薛敏
浙江理工大学理学院,杭州 310018
Author(s):
WANG Jie XUE Min
School of Sciences, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
柱[5]芳烃环氧化X射线衍射柱型空腔
分类号:
O6225.46
文献标志码:
A
摘要:
为了扩大柱[5]芳烃衍生类型,扩展其在主客体化学与分子器件等领域的潜在应用,以1,4二甲氧基柱[3]芳烃[2]醌(或1,4二甲氧基柱[4]芳烃[1]醌)为原料,1,8二氮杂二环十一碳7烯和过氧化叔丁醇为催化剂,制备环氧化醌类柱[5]芳烃,并采用1H NMR、 13C NMR、高分辨质谱和X射线衍射测试其结构性质。结果表明:合成反应条件温和,收率较高,收率分别为81%和42%; 1H NMR实验和X射线衍射法表明,与1,4二甲氧基柱[4]芳烃[1]醌相比,环氧化柱[4]芳烃[1]醌结构中一个对苯二甲醚单元空间位置发生约为90°偏转;而1H NMR数据和结构模拟图表明,环氧化柱[3]芳烃[2]醌中对苯二甲醚单元并未有偏转,成规整的柱型空腔。柱[5]芳烃衍生物及其结构信息为进一步构筑柱[5]芳烃高级组装体奠定基础。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期: 2018-01-26
网络出版日期: 2018-06-22
基金项目: 国家自然科学基金项目(21772178);浙江理工大学科研启动基金;浙江理工大学521人才培养计划
作者简介: 王杰(1990- ),男,山西朔州人,硕士研究生,主要从事超分子化学方面的研究
通信作者: 薛敏,E-mail:minxue@zstu.edu.cn
更新日期/Last Update: 2019-03-13