|本期目录/Table of Contents|

[1]王振,雷中秋,潘忆乐,等.微悬浮聚合法制备的PA/MPS-SiO-2接枝复合胶粒的溶胀性能研究[J].浙江理工大学学报,2017,37-38(自科4):480-484.
　WANG Zhen,LEI Zhongqiu,PAN Yile,et al.Swelling Property of PA/MPSSiO-2 Composite ColloidalParticles Prepared by MicroSuspension Polymerization[J].Journal of Zhejiang Sci-Tech University,2017,37-38(自科4):480-484.
点击复制

微悬浮聚合法制备的PA/MPS-SiO-2接枝复合胶粒的溶胀性能研究()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第37-38卷
期数:
2017年自科4期
页码:
480-484
栏目:
出版日期:
2017-07-10

文章信息/Info

Title:
Swelling Property of PA/MPSSiO-2 Composite ColloidalParticles Prepared by MicroSuspension Polymerization
文章编号:
1673-3851 (2017) 04-0480-05
作者:
王振; 雷中秋; 潘忆乐; 曹志海; 戚栋明
浙江理工大学先进纺织材料与制备技术教育部重点实验室，杭州 310018
Author(s):
WANG Zhen;  LEI Zhongqiu;  PAN Yile;  CAO Zhihai;  QI Dongming
Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
微悬浮聚合; 复合胶粒; 溶胀行为; 交联结构
分类号:
O641-33
文献标志码:
A
摘要:
以原位微悬浮聚合法所制的微米级聚丙烯酸酯PA/MPS偶联改性SiO-2（PA/MPS-SiO-2）接枝复合胶粒为研究对象，利用自带热台的3D视频显微系统在线观察复合胶粒在良溶剂中的尺寸变化情况，并结合索氏抽提实验所测复合胶粒凝胶率的结果，评估复合胶粒的溶胀性能。考察复合胶粒的SiO-2粒子含量、SiO-2表面MPS偶联密度等因素对其溶胀行为的影响，结果表明接枝复合胶粒中存在以接枝SiO-2粒子为交联点的立体网络结构，这是决定接枝复合胶粒溶胀性能的关键因素。

参考文献/References:

［1］ LU H, FEI B, XIN J H, et al. Fabrication of UVblocking nanohybrid coating via miniemulsion polymerization［J］. Journal of Colloid and Interface Science,2006,300(1):111-116.
［2］ ZHU A, SHI Z, CAI A, et al. Synthesis of coreshell PMMASiO-2nanoparticles with suspensiondispersionpolymerization in an aqueous system and its effect on mechanical properties of PVC composites［J］. Polymer Testing,2008,27(5):540-547.
［3］ CHEN X, WU F, MAL A K, et al. New thermally remendable highly crosslinked polymeric materials［J］. Macromolecules,2003,36(6):1802-1807.
［4］ Flory P J. Statistical mechanics of swelling of network structures［J］. The Journal of Chemical Physics.1950,18(1):108-11.
［5］ JAMES H M, GUTH E. Theory of the elastic properties of rubber［J］. The Journal of Chemical Physics.1943,11(10):455-81.
［6］ NANDI S, WINTER H H. Swelling behavior of partially crosslinked polymers: a ternary system［J］. Macromolecules.2005,38(10):4447-55.
［7］ DE SK, ALURU NR, JOHNSON B, et al. Equilibrium swelling and kinetics of pHresponsive hydrogels: Models, experiments, and simulations［J］. Journal of Microelectromechanical Systems.2002,11(5):544-55.
［8］ VALENT  N J L, CARRETEROGONZáLEZ J, MORABARRANTES I, et al. Uncertainties in the determination of crosslink density by equilibrium swelling experiments in natural rubber［J］. Macromolecules,2008,41(13):4717-4729.

备注/Memo

备注/Memo:
收稿日期： 2016-10-13
网络出版日期：2017-01-03
基金项目： 国家自然科学基金项目(51273182)
作者简介： 王振(1991-)，男，山东菏泽人，硕士研究生，主要从事纺织化学品的合成方面的研究
通信作者： 戚栋明，E-mail：dongmingqi@zstu.edu.cn
更新日期/Last Update: 2017-09-25