|本期目录/Table of Contents|

[1]江银枝,孙红英,傅珠婷,等.4-氨基安替比林Cu 2+ 配合物的合成及其催化染料降解[J].浙江理工大学学报,2016,35-36(自科2):159-164.
　JIANG Yinzhi,SUN Huoying,FU Zhuting,et al.Cu 2+  Complexes with 4 Aminoantipyrine：Synthesis  and Catalysis Dye Degradation[J].Journal of Zhejiang Sci-Tech University,2016,35-36(自科2):159-164.
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4-氨基安替比林Cu 2+ 配合物的合成及其催化染料降解()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第35-36卷
期数:
2016年自科2期
页码:
159-164
栏目:
出版日期:
2016-03-10

文章信息/Info

Title:
Cu 2+  Complexes with 4 Aminoantipyrine：Synthesis  and Catalysis Dye Degradation
文章编号:
1673-3851 (2016) 02-0159-06
作者:
江银枝; 孙红英; 傅珠婷; 徐火英
浙江理工大学化学系，杭州 310018
Author(s):
JIANG Yinzhi;  SUN Huoying;  FU Zhuting;  XU Huoying
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
合成; 配合物; 仿生催化; 染料降解; 废水
分类号:
O614
文献标志码:
A
摘要:
合成对苯二甲醛双缩4 氨基安替比林(L 1)，研究其与CuCl 2的配位反应。发现Cu 2+ 催化L 1的分解，得到4 氨基安替比林(L)的Cu配合物CuCl 2L·3H 2O，推测可能的分解机理。利用分光光度法考察CuCl 2L·3H 2O催化酸性蓝9的降解过程，发现配合物能有效催化酸性蓝9的降解，降解过程符合酶促特性，6 h后降解率达到80%。利用HPLC法测定了降解产物，发现降解产物有马来酸。推测可能的降解机理和催化机理，为开发新的染料废水的有效治理技术提供参考。

参考文献/References:

［1］ ROZZI A F E, CELLAMARE C M, BORTONE G. Characterization of textile wastewater and other industrial wastewaters by respirometric and titration biosensors［J］. Wat Sci Tech, 1999, 40(1):161-168.
［2］ AFSANEH S, FATEMEH S, HAMIDREZA S, et al. Facile approach to the synthesis of carbon nanodots and their peroxidase mimetic function in azo dyes degradation［J］. RSC Advances, 2012, 2(12):7367-7370.
［3］ GULAYS H. Process for the removal of recalcitrant organics from industrial wastewater［J］. Wat Sci Tech, 1997, 36(1): 9-16.
［4］ Mehdi B, Erfan O, Hadi S, et al. Preparation and application of chitin and its derivatives: a review［J］. Iran Polym J, 2014, 23(2):307-326.
［5］ ARJUNAN B, KARUPPAN M. A review on fenton and improvements to the fenton process for wastewater treatment［J］. Journal of Environmental Chemical Engineering, 2014, 2(2):557-572.
［6］ SHAMIK C, RAJASEKHAR B. Graphene/semiconductor nanocomposites (GSNs) for heterogeneous photocatalytic decolorization of wastewaters contaminated with synthetic dyes: a review［J］. Applied Catalysis B: Environmental, 2014, 160(2):307-324.
［7］ LEVIN L, MELIGNANI E, RAMOS A M. Effect of nitrogen sources and vitamins on ligninolytic enzyme production by some white rot fungi. Dye decolorization by selected culture filtrates［J］. Bioresource Technology, 2010, 101(12): 4554-4563.
［8］ LAURA C C，JOS LUIS S M，BLANCA E B H. Biodegradation of organic pollutants in saline wastewater by halophilic microorganisms: a review［J］, Environ Sci Pollut Res, 2014, 21(12):9578-9588.
［9］ PHALE P S, BASU A, MAJHI P D, et al. Metabolic diversity in bacterial degradation of aromatic compounds ［J］. Omics, 2007, 11(1): 252-279.
［10］ KULKARNI  M, CHAUDHARI A. Microbial remediation of nitroaromatic compounds: an overview［J］. J Environ Manage, 2007, 85(2): 496-512.
［11］ VERNEKAR M, LELE S S. Laccase properties and applications［J］. Bioresources, 2009, 4(6): 1694-1717.
［12］ CIULLINI I, GULLOTTO A, TILLI S. Enzymatic decolorization of spent textile dyeing baths composed by mixtures of synthetic dyes and additives［J］. Applied Microbiology and Biotechnology, 2012, 96(1):1-11.

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备注/Memo

备注/Memo:
收稿日期： 2015-05-06
基金项目： 国家自然科学基金项目(21472174)；浙江省自然科学基金项目(LY13B010004, LY14B010005)
作者简介： 江银枝(1973-)，女，湖北鄂州人，副教授，博士，主要从事有机化学、配位化学方面的研究
更新日期/Last Update: 2016-06-01