|本期目录/Table of Contents|

[1]周晓俊,邹洋.杂三核配合物［Mg(H2O)4(CuL)2］·4H2O的合成和晶体结构[J].浙江理工大学学报,2013,30(04):595-599.
　ZHOU Xiaojun,ZOU Yang.Synthesis and Crystal Structure of Heterotrinuclear Complex ［Mg(H2O) 4(CuL) 2］·4H2O[J].Journal of Zhejiang Sci-Tech University,2013,30(04):595-599.
点击复制

杂三核配合物［Mg(H2O)4(CuL)2］·4H2O的合成和晶体结构()
分享到：

浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第30卷
期数:
2013年04期
页码:
595-599
栏目:
出版日期:
2013-07-10

文章信息/Info

Title:
Synthesis and Crystal Structure of Heterotrinuclear Complex ［Mg(H2O) 4(CuL) 2］·4H2O
文章编号:
1673-3851 (2013) 04-0595-05
作者:
周晓俊;  邹洋
浙江理工大学理学院, 杭州 310018
Author(s):
ZHOU Xiaojun;  ZOU Yang
School of Sciences, Zhejiang Sci-Tech University, Hangzhou 310018, China
关键词:
金属配体;  水杨醛缩甘二肽席夫碱;  氢键;  杂三核
分类号:
O614.22
文献标志码:
A
摘要:
金属配体［CuL］-(H2L=水杨醛缩甘二肽席夫碱)和MgSO4在水甲醇混合溶液中合成了一个Cu(Ⅱ) Mg(Ⅱ)杂核配合物［Mg(H2O)4(CuL)2］·4H2O。用元素分析、红外光谱等手段对标题配合物的组成和结构进行了表征。该配合物属于三斜晶系,空间群是P-1,晶胞参数:a=7.537(1), b=9.127(2), c=11.728(2), α=73.55(1)°, β=72.43(1)°, γ=84.29(1)°。

参考文献/References:

［1］ Robson R. A net based approach to coordination polymers［J］. Dalton Trans, 2000, 21: 3735-3744.
［2］ Férey G, Mellot Draznieks C, Serre C, et al. A chromium terephthalatebased solid with unusually large pore volumes and surface area［J］. Science, 2005, 309(5743): 2040-2042.
［3］ Liu Y L, Kravtsov V C, Larsen R, et al. Molecular building blocks approach to the assembly of zeolite like metal organic frameworks(ZMOFs) with extra large cavities［J］. Chem Commun, 2006, 14: 1488-1490.
［4］ Xu Y J, Lin L Q, Kanai M, et al. Catalytic asymmetric ring opening of meso aziridines with malonates under heterodinuclear rare earth metal schiff base catalysis［J］. J Am Chem Soc, 2011, 133(15): 5791-5793.
［5］ Wei Z Q, Yue S T, Wang N, et al. Construction of a porous NaCd mixed metalorganic framework based on biphenyl4, 4’dicarboxylate and benzotriazole［J］. Monatsh Chem, 2012, 143(3): 421-425.
［6］ Wang G L, Yang X L, Zhang J, et al. The syntheses of 3d3d mixed heterometallic coordination polymers with magnetic properties［J］. Inorg Chem Commun, 2008, 11(12): 1430-1432.
［7］ Martínez Lillo J, Delgado F S, RuizPérez C, et al. Heterotrimetallic oxalatobridged Re IV 2M II complexes(M=Mn, Co, Ni, Cu): synthesis, crystal structure, and magnetic properties［J］. Inorg Chem, 2007, 46(9): 3523-3530.
［8］ Singh N H, Prasad A, Sinha R K. Synthesis, characterization and conducting properties of complex salts and heterobimetallic coordination polymers of the cyanodithioimidocarbonato ligand［J］. Inorg Chem Commun, 2006, 9(10): 1058-1062.
［9］ Wang G L, Yang X L, Liu Y, et al. A 3d3d heterometallic organic framework consisting of two crosslinked coordination polymers［J］. Inorg Chem Commun, 2008, 11(7): 814-817.
［10］ Ren P, Shi W, Cheng P. Synthesis and characterization of threeDimensional 3d3d and 3d4f heterometallic coordination polymers with high thermal stability［J］. Cryst Growth Des, 2008, 8(4): 1097-1099.
［11］ Kitaura R, Onoyama G, Sakamoto H, et al. Immobilization of a metallo schiff base into a microporous coordination polymer［J］. Angew Chem Int Ed, 2004, 43(20): 2684-2687.
［12］ Huang Y G, Wu M Y, Lian F Y, et al. Two fold interpenetration corrugated brick wall frameworks of 3d4f heterometallic coordination polymers［J］. Inorg Chem Commun, 2008, 11(8): 840-842.
［13］ 陈春华, 陆茜. L半胱氨酸席夫碱及其铜、锌配合物的合成及表征［J］. 湖北化工, 1998(5): 18-19.
［14］ 冯小珍, 夏金虹, 刘峥. 双核铜(Ⅱ)β丙氨酸缩水杨醛席夫碱配合物的合成及其性质［J］. 桂林工学院学报, 2007, 27(4): 562-564.
［15］ Casella L, Gullotti M. Synthesis, sterochemistry and oxygenation of cobalt(Ⅱ)pyridoxal model complexes: a new family of chiral dioxygen carriers［J］. Inorg Chem, 1986, 25(9): 1293-1303.
［16］ Gruning C, Schmidt H, Rehder D. A water soluble, neutral {aquaVV}2 complex with a biomimetic ONO ligand set［J］. Inorg Chem Commun, 1999, 2(2): 57-59.

［17］ GarciaRaso A, Fiol J J, LopezZafra A, et al. Synthesis of Zn Nsalicylidene Laminoacidatos: Xray structure of［(N salicylidene Lalaninato)(aqua)zinc(II)］. 0.25H2O and［(N salicylidene L valinato)(aqua) zinc(II)］［J］. Polyhedron, 2000, 19(6): 673-680.
［18］ Mondal S, Rath S P, Rajak K K, et al. A family of(N Salicylidene α amino acidato)vanadate esters incorporating chelated propane1, 3diol and glycerol: synthesis, structure, and reaction［J］. Inorg Chem, 1998, 37(8): 1713-1719.
［19］ 苏扬, 臧双全, 倪春林, 等. 过渡金属碱土金属铜钙四核配合物Cu2Ca2L2(H2O)6·2H2O的合成和晶体结构［J］. 无机化学学报, 2004, 20(7): 846-848.
［20］ Zou Y, Jiang Y Z. A ladderlike coordination polymer［Sr(H2O)4(CuL)2］·(CuL)·2. 25H2O constructed from metallo ligand Na［CuL］ and Sr(NO3)2: crystal structure and ESR study［J］. J Inorg Organomet Polym, 2011, 21(1): 165-170.
［21］ Zou Y, Liu W L, Gao S, et al. A novel molecular ladder structure of Cu(Ⅱ)Ba(Ⅱ) coordination polymer exhibiting ferromagnetic coupling［J］. Chem Commun, 2003(23): 2946-2947.
［22］ Ueki T, Ashida T, Sasada V, et al. Crystal structure of Nsalieylideneglyeinatoaquoeopper(II)tetrahydrate［J］. Acta Crystallogr Sect B: Struct Sci, 1969, 25(2): 328-335.

备注/Memo

备注/Memo:
收稿日期： 2012-11-02
基金项目： 国家自然科学基金资助项目(20901067);浙江省自然科学基金资助项目(Y4080342)
作者简介： 周晓俊(1985-),女,河南新乡人,硕士研究生,研究方向为金属有机框架的设计合成和吸附性能研究。
通信作者： 邹洋,电子邮箱:zouyang@zstu.edu.cn
更新日期/Last Update: 2013-10-24