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[1]侯锐刚a,b,易玲敏a,等. 含聚苯乙烯侧链的两亲性有机硅接枝共聚物的合成与表征[J].浙江理工大学学报,2011,28(06):831-835.
　HOU Rui ganga,b,YI Ling mina,et al. Synthesis and Characterization of Amphiphilic Silicone Graft Copolymers Containing Polystyrene SideChain[J].Journal of Zhejiang Sci-Tech University,2011,28(06):831-835.
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 含聚苯乙烯侧链的两亲性有机硅接枝共聚物的合成与表征()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第28卷
期数:
2011年06期
页码:
831-835
栏目:
(自科)纺织与服装工程
出版日期:
2011-12-30

文章信息/Info

Title:
 Synthesis and Characterization of Amphiphilic Silicone Graft Copolymers Containing Polystyrene SideChain
文章编号:
16733851 (2011) 06083105
作者:
侯锐刚a; b;  易玲敏a; b;  林鹤鸣a; b;  黄传霞a; b
 浙江理工大学, a. 生态染整技术教育部工程研究中心; b. 先进纺织材料与制备技术教育部重点实验室, 杭州 310018
Author(s):
 HOU Ruiganga; b;  YI Lingmina; b;  LIN Heminga; b;  HUANG Chuanxiaa; b
 Zhejiang SciTech University, a. Engineering Research Center for EcoDyeing & Finishing of Textiles, Ministry of Education; b. The Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Hangzhou 310018, China
关键词:
 ; 阴离子聚合;  硅氢加成;  聚苯乙烯;  两亲性有机硅接枝共聚物
分类号:
O631
文献标志码:
A
摘要:
    在甲苯溶剂中，以正丁基锂（nBuLi）为引发剂，运用阴离子聚合制备端乙烯基聚苯乙烯大分子单体（VPS）；在四氢呋喃（THF）溶剂中，通过含氢硅油与VPS、端烯丙基聚醚（APE）及烯丙基缩水甘油醚（AGE）的硅氢加成反应，合成了含聚苯乙烯（PS）侧链的两亲性有机硅接枝共聚物，并通过GPC、1HNMR、FTIR等测试手段对接枝共聚物结构进行了表征。所得聚合物可作为一种多功能型的有机颜料分散剂，用于颜料印花。

参考文献/References:

 ［1］ 周春隆, 穆振义. 有机颜料： 结构、特性及应用［M］. 北京: 化学工业出版社, 2002.
［2］ Lelu S, Novat C, Graillat C, et al. Encapsulation of an organic phthalocyanine blue pigment into polystyrene latex particles using a miniemulsion polymerization process［J］. Polym Int, 2003, 52(4): 542547.
［3］ Bulychev N A, Arutunov I A, Zubov V P, et al. Block copolymers of vinyl ethers as thermoresponsive colloidal stabilizers of organic pigments in aqueous media［J］. Macromol Chem Phys, 2004, 205(18): 24572463.
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［6］ Reuter E, Dr Silber S, Dr Psiorz C. The use of new blockcopolymeric dispersing agents for waterborne paints—theoretical and practical aspects［J］. Prog Org Coat, 1999, 37(3/4): 161167.
［7］ Svitova T, Hoffmann H, Randal M. Hill. Trisiloxane surfactants: surface/interfacial tension dynamics and spreading on hydrophobic surfaces［J］. Langmuir, 1996, 12(7): 17121721.
［8］ Riess G. Micellization of block copolymers［J］. Prog Polym Sci, 2003, 28(7): 11071170.
［9］ Alexandridis P, Lindman B. Amphiphilic Block Copolymers: SelfAssembly and Applications［M］. Elsevier: Amsterdam, 2000.
［10］ Masehke U, Wagner T, Coqueret X. Synthesis of highmolecularweight poly(dimethylsiloxnae) of uniform size by anionic polymerization, 1. initiation by a monofunctional lithium siloxanolate［J］. Macromol Chem Phys, 1992, 193(9): 24532466.

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备注/Memo

备注/Memo:
 收稿日期： 2010-11-30
基金项目： 国家自然科学基金(2060629);浙江省自然科学基金(Y4090579);浙江理工大学科研启动基金(0701652Y)
作者简介： 侯锐刚（1985-），男，陕西宝鸡人，硕士研究生，主要从事新型纺织化学品的合成研究。
通讯作者： 易玲敏，电子邮箱：lmyi@zstu.edu.cn
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