|本期目录/Table of Contents|

[1]丁燕,邵建中,邵敏. 高效液相色谱研究C.I.Reactive Blue 194的水解性能[J].浙江理工大学学报,2011,28(03):328-332.
　DING Yan,SHAO Jian zhong,SHAO Min. A Study on Hydrolysis of C.I. Reactive Blue 194 by High Performance Liquid Chromatography[J].Journal of Zhejiang Sci-Tech University,2011,28(03):328-332.
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 高效液相色谱研究C.I.Reactive Blue 194的水解性能()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第28卷
期数:
2011年03期
页码:
328-332
栏目:
(自科)纺织与服装工程
出版日期:
2011-06-30

文章信息/Info

Title:
 A Study on Hydrolysis of C.I. Reactive Blue 194 by High Performance Liquid Chromatography
文章编号:
16733851 (2011) 03032805
作者:
 丁燕;  邵建中;  邵敏
 浙江理工大学先进纺织材料与制备技术教育部重点实验室， 杭州 310018
Author(s):
 DING Yan;  SHAO Jianzhong;  SHAO Min
 The Key Laboratory of Advanced Textile Materials and Manufacturing Technology(Zhejiang SciTech University), Ministry of Education, Hangzhou 310018, China
关键词:
 ; 活性染料;  高效液相色谱;  水解
分类号:
TS193.1
文献标志码:
A
摘要:
     应用高效液相色谱研究异双官能团（VS/MCT）型活性染料C.I.Reactive Blue 194在不同条件下的水解行为及其水解动力学，结果表明：C.I.Reactive Blue 194的两个活性基VS和MCT在碱性下均发生水解，染料的主要水解产物有3种，即染料的VS、MCT活性基分别被水解及同时被水解的产物；同时，染料的水解过程中还伴随有亚胺基桥基的断裂。研究同时证实了C.I.Reactive Blue 194的总水解反应为准一级动力学反应，随着pH和温度的增加，染料水解速率递增。

参考文献/References:

 ［1］ 宋心远. 多组分纺织品活性染料生态染色技术: 一［J］. 印染, 2009（11）: 4346.
［2］ 宋心远, 沈煜如. 活性染料的色牢度及其影响因素: 一［J］. 印染, 2006（11）: 4144.
［3］ 王正佳, 邵敏, 邵建中. 乙烯砜型活性染料水解动力学的HPLC研究［J］. 纺织学报, 2006, 27(9): 913.
［4］ 邵敏, 邵建中. 丝素与一氯均三嗪型活性染料反应性的HPLC研究［J］. 纺织学报, 2007, 28(4): 8387.
［5］ Liu Dongzhi, Gao Kunyu, Cheng Lubai. The hydrolysis kinetics and dyeing propertie of 3~carboxypyridinotriazine reactive dyes［J］. Dyes and Pigments, 1997, 33(4): 8796.
［6］ MAJA Klannik. The influence of temperature on the kinetics of concurrent hydrolysis and methanolysis reactions of a monochlorotriazine reactive dye［J］. Dyes and Pigments, 2000, 46: 915.
［7］ Morita Z, Yamada A, Shigehara K, et al. The hydrolysis of the reactive groups, and side reaction for a mixed bifunctional reactive dye (C. I. Reactive Red 194) and related compounds［J］. Dyes and Pigments, 1996, 30(2): 151171.

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备注/Memo

备注/Memo:
 收稿日期： 2010-07-23
作者简介： 丁燕(1986-)，女，江苏南通人，硕士研究生，主要从事染整理论和染整新技术研究。
通讯作者： 邵建中，电子邮箱：jshao@zstu.edu.cn
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