|本期目录/Table of Contents|

[1]魏松林,伍贤方,郑旭明. 乙酰丙酮锌激发态动态结构的共振拉曼光谱研究[J].浙江理工大学学报,2011,28(01):140-146.
　WEI Song lin,WU Xian fang,ZHENG Xu ming. Resonance Raman Spectroscopic Investigation of Excited State Dynamic Structure of Znic Bisacetylacetone[J].Journal of Zhejiang Sci-Tech University,2011,28(01):140-146.
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 乙酰丙酮锌激发态动态结构的共振拉曼光谱研究()
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浙江理工大学学报[ISSN:1673-3851/CN:33-1338/TS]

卷:
第28卷
期数:
2011年01期
页码:
140-146
栏目:
(自科)生物与生命科学
出版日期:
2011-02-28

文章信息/Info

Title:
 Resonance Raman Spectroscopic Investigation of Excited State Dynamic Structure of Znic Bisacetylacetone
文章编号:
16733851 (2011) 01014007
作者:
 魏松林;  伍贤方;  郑旭明
 浙江理工大学理学院， 杭州 310018
Author(s):
 WEI Songlin;  WU Xianfang;  ZHENG Xuming
 School of Sciences, Zhejiang SciTech University, Hangzhou 310018, China
关键词:
 ; 乙酰丙酮锌;  密度泛函理论;  共振拉曼光谱;  激发态动态结构
分类号:
O643.12
文献标志码:
A
摘要:
    研究乙酰丙酮锌激发态动力学及反应机理对理解和控制沉积膜的成分及形态具有重要意义。运用共振拉曼技术结合密度泛函理论研究乙酰丙酮锌的激发态动力学，对乙酰丙酮锌的振动光谱进行了指认，对乙酰丙酮锌在甲醇中285 nm处的电子吸收带进行归属。获得了282.4 nm处乙酰丙酮锌在甲醇溶液中的共振拉曼光谱。结果表明，乙酰丙酮锌的激发态动态结构包含6个全对称振动模，起决定作用的是υ11、υ10、υ7和υ6振动模。注意到了乙酰丙酮锌和乙酰丙酮铜共振拉曼光谱中υ4、υ10、υ11振动模的相对强度变化，以及非全对称模在其激发态动力学过程中的作用。

参考文献/References:

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［4］ Doppelt P, Baum T H. Chemical vapor deposition of copper for IC metallization: precursor chemistry and molecular structure［J］. MRS Bull, 1994, 19(8): 4148.
［5］ Gafney H D, Lintvedt R L. Photochemical reactions of copper(II)1,3diketonate complexes［J］. J Am Chem Soc, 1971, 93(7): 16231628.
［6］ Fackler J P, Cotton F A, Barnum D W. Electronic spectra of βdiketone complexes III. αSubstituted βdiketone complexes of copper(II)［J］. Inorg Chem, 1963, 2(1): 97101. 
［7］ Fackler J P, Cotton F A. Electronic spectra of βdiketone complexes. IV. γsubstituted acetylacetonates of copper(II)［J］. Inorg Chem, 1963, 2(1): 102106.
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备注/Memo

备注/Memo:
 收稿日期： 2010-01-25
基金项目： 国家自然科学基金(20573097)；浙江省自然科学基金(R405465)
作者简介： 魏松林(1980-)，男，河南驻马店人，硕士研究生，主要从事光化学反应动力学研究
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